کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7924124 | 1511938 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis, electrical and dielectrical properties of (LixNa1-x)6Mg(SO4)4 vanthoffite ceramics as new attractive electrode materials for Li- and Na-ion batteries
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
(LixNa1âx)6Mg(SO4)4 ceramics denoted as LNMSx (xâ¯=â¯0.1, 0.3, 0.5, 0.7 and 1â¯mol%) were obtained via the solid state reaction method. The refinement of the structural parameters using the Fullprof software by the Rietveld method confirmed that the Li+ dopant can replace the sodium in this structure with a slight increase in the lattice parameters. The spectroscopic studies revealed the vibrational mode of the sulfate groups. Electrical conductivity, activation energies, modulus and dielectric properties were studied by impedance spectroscopy in the [553-733â¯K] temperature range. Results show that the materials present a semiconductor ionic character with 1D conduction by means of migration of cation mobile in the system. Conductivity decreases when the Li+ dopant content x increases. The electrochemical studies show that LNMSx (xâ¯=â¯0.5) has the highest electrical conductivity that can be proposed as a good electrolyte material for lithium or sodium batteries applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Science and Engineering: B - Volume 228, February 2018, Pages 224-233
Journal: Materials Science and Engineering: B - Volume 228, February 2018, Pages 224-233
نویسندگان
Abir Bejaoui, Ahmed Souamti, Massoud Kahlaoui, Antonio Diego Lozano-GorrÃn, Dalila Ben Hassen Chehimi,