کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7951898 1513700 2018 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Solvothermal-assisted morphology evolution of nanostructured LiMnPO4 as high-performance lithium-ion batteries cathode
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد شیمی مواد
پیش نمایش صفحه اول مقاله
Solvothermal-assisted morphology evolution of nanostructured LiMnPO4 as high-performance lithium-ion batteries cathode
چکیده انگلیسی
As a potential substitute for LiFePO4, LiMnPO4 has attracted more and more attention due to its higher energy, showing potential application in electric vehicle (EV) or hybrid electric vehicle (HEV). In this work, solvothermal method was used to prepare nano-sized LiMnPO4, where ethylene glycol was used as solvent, and lithium acetate (LiAc), phosphoric acid (H3PO4) and manganese chloride (MnCl2) were used as precursors. The crystal structure and morphology of the obtained products were characterized by X-ray diffraction, scanning electron microscopy and transmission electron microscopy. The electrochemical performance was evaluated by charge-discharge cycling, cyclic voltammetry and electrochemical impedance spectroscopy. The results show that the molar ratio of LiAc:H3PO4:MnCl2 plays a critical role in directing the morphology of LiMnPO4. Large plates transform into irregular nanoparticles when the molar ratio changes from 2:1:1 to 6:1:1. After carbon coating, the product prepared from the 6:1:1 precursor could deliver discharge capacities of 156.9, 122.8, and 89.7 mAh g−1 at 0.05C, 1C and 10C, respectively. The capacity retention can be maintained at 85.1% after 200 cycles at 1C rate for this product.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Materials Science & Technology - Volume 34, Issue 9, September 2018, Pages 1544-1549
نویسندگان
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