کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
7954208 1513768 2017 9 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
The effect of nitrogen and/or boron doping on the electrochemical performance of non-caking coal-derived activated carbons for use as supercapacitor electrodes
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد شیمی مواد
پیش نمایش صفحه اول مقاله
The effect of nitrogen and/or boron doping on the electrochemical performance of non-caking coal-derived activated carbons for use as supercapacitor electrodes
چکیده انگلیسی
Coal-based activated carbons doped with either N or B or a combination of the two were prepared for use as the electrode materials of supercapacitors by ball milling and subsequent activation using Xinjiang non-caking coal, melamine and boric acid as the respective carbon, nitrogen and boron sources. FTIR spectroscopy and XPS reveal that the B and N atoms are substitutionally incorporated into the carbon skeleton. These doped activated carbons contain a large number of mesopores. Cyclic voltammetry, galvanostatic charge/discharge and electrochemical impedance spectroscopy show that N- and B-doped activated carbons have a superior capacitance and rate performance to the non-doped one. The B-N co-doped material has the highest specific capacitance of 176 F g−1 at 0.5 A g−1, which is attributed to a synergistic effect of B-N co-doping. The capacitance of the co-doped sample remains at 96% of the original value after 20 000 cycles.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: New Carbon Materials - Volume 32, Issue 5, October 2017, Pages 442-450
نویسندگان
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