کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7969129 | 1514345 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
TEM study the corrosion behavior of the low alloy steels developed for flue gas desulfurization system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: TEM study the corrosion behavior of the low alloy steels developed for flue gas desulfurization system TEM study the corrosion behavior of the low alloy steels developed for flue gas desulfurization system](/preview/png/7969129.png)
چکیده انگلیسی
This study investigated the corrosion behavior and underline mechanisms of low alloy steels with a minor addition of 0.4â¯wt% Cu, 0.2â¯wt% Ni, 0.1â¯wt% Sb and 0.05â¯wt% Co developed for a flue gas desulfurization (FGD) system. Corrosion tests were carried out in an aggressive solution of 16.9â¯vol% H2SO4â¯+â¯0.35â¯vol% HClâ¯+â¯Bal. H2O at 60â¯Â°C for up to 48â¯h. The experimental results revealed enrichment of the additional elements (Cu, Sb and Ni) in the corrosion layer, whose concentration increased with test time. As the concentrations of Cu increased, the crystallization and growth of the Cu particles (from several nm to 320â¯nm)) within the corrosion layer was accelerated. At the initial stage of the test, a continuous amorphous layer rich with the additional elements formed and covered the surface of the steel, which then gradually developed defects, pores and cracks, as the crystallization and growth of Cu particles with the elapse of time. The results indicated that the corrosion resistance of the low alloy steel depends on the existence form of Cu in the corrosion layer, i.e., as solute atoms or as nanoparticles strengthened the corrosion layer and increased corrosion resistance. As the coarsening of Cu particles weakened the corrosion layer and deteriorated the corrosion resistance.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Characterization - Volume 142, August 2018, Pages 540-549
Journal: Materials Characterization - Volume 142, August 2018, Pages 540-549
نویسندگان
Yinsheng He, Keun-Bong Yoo, Joong Cheul Park, Byung-Ho Lee, Jeong-Bong Yoon, Jung-Gu Kim, Keesam Shin,