کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
7988374 | 1515817 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Design of highly efficient Ni-based water-electrolysis catalysts by a third transition metal addition into Ni3Mo
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Design of highly efficient Ni-based water-electrolysis catalysts by a third transition metal addition into Ni3Mo Design of highly efficient Ni-based water-electrolysis catalysts by a third transition metal addition into Ni3Mo](/preview/png/7988374.png)
چکیده انگلیسی
The surface composition segregation can have important effects on the catalytic and electrochemical properties of an alloy catalyst. We have performed density-functional theory (DFT) calculations to investigate the effects of a third transition metal (M) addition into the Ni3Mo alloy on the surface segregation and the stability of bulk-terminated and Ni-segregated Ni3Mo/M(111) surfaces. The third transition metals (MTc, Ru, W, Re, or Os) are found to enhance the Ni surface segregation, while MTi, V, Cr, Mn, Fe, Co, Cu, Nb, Rh, Hf, Ta, or Ir retain the Ni-segregated surface but weaken the Ni surface segregation tendency. The remaining transition metals (MSc, Zn, Y, Zr, Pd, Ag, Cd, Pt, or Au) show a complete suppression of the Ni surface segregation. We find the transition metals (Ti, V, Cr, Mn, Fe, Co, Cu, Hf, and W) can stabilize a special atomic configuration that is predicted to have an outstanding catalytic performance for water electrolysis. Furthermore, we analyze the factors that control the Ni surface segregation behavior in the Ni3Mo/M(111) surface. The present study provides useful theoretical guide for developing highly active Ni-Mo-M hydrogen evolution electrodes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Intermetallics - Volume 94, March 2018, Pages 99-105
Journal: Intermetallics - Volume 94, March 2018, Pages 99-105
نویسندگان
Yanlin Yu, Qiang Hu, Wei Xiao, Jianwei Wang, Ligen Wang,