کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8012166 | 1516939 | 2016 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
High-temperature glassy-ceramic sealants SiO2-Al2O3-BaO-MgO and SiO2-Al2O3-ZrO2-CaO-Na2O for solid oxide electrochemical devices
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
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چکیده انگلیسی
Glasses of the SiO2-Al2O3-BaO-MgO and SiO2-Al2O3-ZrO2-CaO-Na2O systems were synthesized in the perspective to apply them as sealants in SOFC at operating temperatures of 700-900 °C. Thermal properties of the chosen glass compositions and their compatibility with the SOFC materials (YSZ-electrolyte and alloy-interconnector Crofer22APU, 15Ã25T) were investigated by means of synchronic thermal analysis and high-temperature dilatometry. The elemental analysis was performed by atomic emission spectroscopy. The average values of the temperature coefficients of the linear extension are 10.0Ã10â6 °Câ1 for glass 45%SiO2- 15%Al2O3-25%BaO-15%MgO and 9.5Ã10â6 °Câ1 for glass 60%SiO2-10%Al2O3-10%ZrO2-5%CaO-15%Na2O. The gluing microstructure in YSZ/glass/Crofer22APU was studied by scanning electron microscopy. The crystallization process of silicate phases was revealed to occur in the SiO2-Al2O3-BaO-MgO glass. The analysis of the crystallization products was performed by Raman spectroscopy and X-ray diffraction. Glassy ceramics was proved to possess better parameters in comparison with amorphous glass to be used as a sealant in electrochemical sensors and oxygen sensors. The SiO2-Al2O3-ZrO2-CaO-Na2O low-temperature amorphous glass can be applied in SOFC.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Transactions of Nonferrous Metals Society of China - Volume 26, Issue 11, November 2016, Pages 2916-2924
Journal: Transactions of Nonferrous Metals Society of China - Volume 26, Issue 11, November 2016, Pages 2916-2924
نویسندگان
S. QI, N.M. POROTNIKOVA, M.V. ANANYEV, A.V. KUZMIN, V.A. EREMIN, A.A. PANKRATOV, N.G. MOLCHANOVA, O.G. REZNITSKIKH, A.S. FARLENKOV, E.G. VOVKOTRUB, Yu.P. ZAIKOV,