کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8012219 | 1516940 | 2016 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Theoretical simulation and experimental study of hydrolysis separation of SbCl3 in complexation-precipitation system
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
فلزات و آلیاژها
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The theoretical simulation and verified experiments on metal separation in a Sb3+-OHâ-Clâ complexation-precipitation system involving hydrolysis-precipitation reactions of SbOCl, Sb4O5Cl2 and Sb2O3 were carried out. The equilibrium concentration of [Sb3+]T was obtained by calculation and verified by experiments. The precipitates SbOCl, Sb4O5Cl2 and Sb2O3 were analyzed through the equilibrium concentration of Sb3+ in the solution and the ÎrGÎm of transformation reactions of these materials. It is found that the concentration of [Sb3+]T in verified experiments was larger than the theoretical value, where the theoretical minimum concentration of [Sb3+]T was 10â10.92 mol/L at pH value of 4.6 and the minimum concentration obtained from the verified experiment was about 10â3.8 mol/L at pH value of 5.1. Different precipitates can be obtained at certain pH. The SbOCl cannot be obtained both in theoretic calculations and in verified experiments, while the Sb8O11Cl2·H2O was generated in the experiment.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Transactions of Nonferrous Metals Society of China - Volume 26, Issue 10, October 2016, Pages 2746-2753
Journal: Transactions of Nonferrous Metals Society of China - Volume 26, Issue 10, October 2016, Pages 2746-2753
نویسندگان
Qing-hua TIAN, Yun-tao XIN, Li YANG, Xue-hai WANG, Xue-yi GUO,