Transparent plastic scintillators for neutron detection based on lithium salicylate

Transparent plastic scintillators with pulse shape discrimination containing 6Li salicylate have been synthesized by bulk polymerization with a maximum 6Li loading of 0.40 wt%. Photoluminescence and scintillation responses to gamma-rays and neutrons are reported herein. Plastics containing 6Li salicylate exhibit higher light yields and permit a higher loading of 6Li as compared to previously reported plastics based on lithium 3-phenylsalicylate. However, pulse shape discrimination performance is reduced in lithium salicylate plastics due to the requirement of adding more nonaromatic monomers to the polymer matrix as compared to those based on lithium 3-phenylsalicylate. Reduction in light yield and pulse shape discrimination performance in lithium-loaded plastics as compared to pulse shape discrimination plastics without lithium is interpreted in terms of energy transfer interference by the aromatic lithium salts.