کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
821406 | 906758 | 2008 | 8 صفحه PDF | دانلود رایگان |
![عکس صفحه اول مقاله: The influence of functionalized MWCNT reinforcement on the thermomechanical properties and morphology of epoxy nanocomposites The influence of functionalized MWCNT reinforcement on the thermomechanical properties and morphology of epoxy nanocomposites](/preview/png/821406.png)
The nature of the interphase, often considered the third phase of nanocomposites, has been a central topic in nanocomposites research. In this study, an ionic bonding scheme was employed to graft epoxy-compatible amine terminated linear polypropylene oxide (A-PPO) molecules of different molecular weight to oxidized multi-walled carbon nanotubes (o-MWCNTs), and thereby modify the interphase of MWCNT-epoxy nanocomposites. The amine-cured epoxy systems reinforced with different functionalized MWCNTs demonstrated divergent thermomechanical properties. Fractography revealed distinct fracture behaviour for nanocomposites with long-chain A-PPO modified MWCNTs. The results demonstrate the feasibility of interphase control and performance engineering through the judicious choice of polymer grafts.
Journal: Composites Science and Technology - Volume 68, Issue 12, September 2008, Pages 2535–2542