The units-Picard complex and the Brauer group of a product

We introduce the relative units-Picard complex of an arbitrary morphism of schemes and apply it to the problem of describing the (cohomological) Brauer group of a (fiber) product of schemes in terms of the Brauer groups of the factors. Under appropriate hypotheses, we obtain a five-term exact sequence involving the preceding groups which enables us to solve the indicated problem for, e.g., certain classes of varieties over a field of characteristic zero.