کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
8943115 | 1645134 | 2018 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Selective localization of carbon nanotube and organoclay in biodegradable poly(butylene succinate)/polylactide blend-based nanocomposites with enhanced rigidity, toughness and electrical conductivity
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
سرامیک و کامپوزیت
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چکیده انگلیسی
Carbon nanotube (CNT) and organo-montmorillonite (15A) were used individually and simultaneously as reinforcing fillers to fabricate poly(butylene succinate)/polylactide (PBS/PLA) blend-based nanocomposites. Poly(butylene succinate-co-lactate) served as compatibilizer for the PBS/PLA blend. Morphological results demonstrated that the added CNT was distributed mainly in the PBS matrix, whereas the added 15A was selectively localized within the dispersed PLA domains. Adding only 15A produced a quasi co-continuous PBS-PLA morphology. DSC results confirmed the nucleation effect of CNT on the crystallization of PBS and PLA, whereas 15A facilitated only the nucleation of PLA. The CNT exerted greater influence than 15A on the samples' rheological properties. The Young's modulus and impact strength of the nanocomposites increased up to 4.2 and 2.8 times, respectively, compared with those of the blend. The electrical resistivity of the blend decreased by up to 11 orders at 3â¯phr CNT loading. The electrical-percolation threshold was constructed at 0.5â¯phr CNT loading.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Composites Part A: Applied Science and Manufacturing - Volume 114, November 2018, Pages 30-39
Journal: Composites Part A: Applied Science and Manufacturing - Volume 114, November 2018, Pages 30-39
نویسندگان
Veluri Sivanjineyulu, Kartik Behera, Yen-Hsiang Chang, Fang-Chyou Chiu,