کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9577506 1505190 2005 6 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Nuclear magnetic dipole moments from NMR spectra
موضوعات مرتبط
مهندسی و علوم پایه شیمی شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
Nuclear magnetic dipole moments from NMR spectra
چکیده انگلیسی
In the procedure applied to extract the magnetic dipole moments of bare nuclei from NMR spectra of molecules the shielding of nuclei by electrons has been often described in a very crude manner. We determine the moments for 13C, 14N, 15N, 17O, 19F, 31P and 33S using more accurate shielding constants. Our gas phase NMR data are next used to improve the accuracy of the moments of 13C, 17O, 19F and 33S nuclei. We present a new, systematic analysis of the results, based on the relations between the nuclear magnetic dipole moments, the resonance frequencies and the shielding constants.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Chemical Physics Letters - Volume 411, Issues 1–3, 5 August 2005, Pages 111-116
نویسندگان
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