کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9594878 | 1395913 | 2005 | 10 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Photocatalytic reduction of oxygen molecules at the (1Â 0Â 0) TiO2 anatase surface
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
شیمی تئوریک و عملی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The adsorption, photoreduction and chemical activity of oxygen molecules on the (1Â 0Â 0) anatase surface have been investigated here together with the effects that surface oxygen vacancies (VO) can have on these O2-related processes. We use an original approach by treating molecules on the TiO2 surface like surface defects in the same framework successfully used for defects in semiconductors. The achieved results: (i) give the first theoretical evidence of an acceptor behaviour of an adsorbed O2 molecule, which is at the origin of its photoreduction; (ii) show that the VO donor character is strongly affected by the interaction with O2; and (iii) suggest that the release of O2-1 radicals as well as the formation of O2-related radicals may be favoured by photogenerated electrons in presence of surface VO's.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Surface Science - Volume 577, Issue 1, 20 February 2005, Pages 59-68
Journal: Surface Science - Volume 577, Issue 1, 20 February 2005, Pages 59-68
نویسندگان
A. Amore Bonapasta, F. Filippone,