کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9607791 | 46028 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Catalytic activities and surface properties of zeolite-supported molybdenum nitrides for NO reduction with H2
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
A series of zeolite (H-ZSM-5)-supported molybdenum nitride catalysts with Mo loading ranging from 2 to 30Â wt.% were synthesized by temperature-programmed nitridation in a flow of NH3. The surface properties of the nitride samples were characterized by XPS, H2-TPR, and XRD techniques and their catalytic activities were evaluated for NO reduction with H2. For the fresh samples, molybdenum nitrides coexisted with oxides on the zeolite. With the increase of Mo loading from 2 to 30Â wt.%, the degree of nitridation increased linearly with the increase of Mo loading. We observed that a catalyst with higher Mo loading exhibited higher initial activities. The nitrided 2Â wt.% Mo/H-ZSM-5 catalyst was the most stable and NO conversion to N2 remained unchanged within a test period of 15Â h. For the catalysts with Mo loading above 2Â wt.%, catalytic activities decreased with time on stream. After 15Â h, the nitrided 2Â wt.% Mo/H-ZSM-5 catalyst was the most active among the tested catalysts. The results of H2-TPR measurements for the used and oxygen-saturated catalysts revealed that catalyst deactivation was a result of oxygen incorporation into the nitride lattices. The strong interaction between the molybdenum species and H-ZSM-5 zeolite as well as the lowering of H2-reduction temperature of surface oxygen might be the reasons for the good performance of the nitrided 2Â wt.% Mo/H-ZSM-5 catalyst for NO reduction with H2.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 293, 28 September 2005, Pages 83-90
Journal: Applied Catalysis A: General - Volume 293, 28 September 2005, Pages 83-90
نویسندگان
C. Shi, A.M. Zhu, X.F. Yang, C.T. Au,