کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9607950 | 46058 | 2005 | 14 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Rh/fibre catalyst for ethene hydroformylation: Catalytic activity and characterisation
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
A fibre-supported Rh-phosphine catalyst, Fibrecatâ¢, was tested in hydroformylation of ethene and characterised by spectroscopic methods (NMR, DRIFT) before reaction, after pretreatments and after reaction. Fibrecat⢠was an active and selective catalyst with 95% selectivity for propanal at 100 °C and 0.5 MPa. Higher temperatures were required to obtain similar activity with unmodified Rh/C and Rh/SiO2 catalysts, and propanal selectivities remained less than 50%. 31P NMR characterisations suggested that two kinds of Rh-P species were formed on Fibrecat⢠during the catalyst preparation: a monophosphine species, Rh(acac)(CO)(PS-PPh2), and a diphosphine species, Rh(CO)2(PS-PPh2)2. An activation period of 5-10 h at the beginning of the reaction on Fibrecat⢠was required for transformation of the monophosphine and diphosphine species in contact with CO/H2 to the active Rh-carbonyl hydrides. Evidently, Rh supported on phosphine-modified fibre forms catalytically active Rh-phosphine species with superior activity and selectivity to unmodified Rh catalysts and clearly higher activity than Rh-phosphine supported on silica.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 285, Issues 1â2, 10 May 2005, Pages 96-109
Journal: Applied Catalysis A: General - Volume 285, Issues 1â2, 10 May 2005, Pages 96-109
نویسندگان
T.A. Zeelie, A. Root, A.O.I. Krause,