کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9608144 | 46074 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Tunable dimerization of α-methylstyrene catalyzed by acidic ionic liquids
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Dimerization of α-methylstyrene (AMS) catalyzed by ionic liquids and the effects of different organic solvents on the catalytic reaction were investigated. The results show that ionic liquids such as alkylaminium-chloroaluminate and alkylaminium-ferric chloride are effective catalysts for the dimerization. AMS conversion of 100% was achieved when using alkylaminium-chloroaluminate chloride as catalyst. The selectivity of saturated dimer 1,1,3-trimethyl-3-phenylindan is as high as about 97% in the absence of organic solvents. Moreover, the raw material was mainly converted to unsaturated dimers 4-methyl-2,4-diphenyl-1-pentene and 4-methyl-2,4-diphenyl-2-pentene in the presence of several polar solvents such as tertiary amyl alcohol or tertiary butanol, although the reaction rate of the AMS conversion became much lower. Thus, AMS dimerization can be tuned to produce either cyclic dimers or linear dimers by adding polar solvents or omitting them.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 279, Issues 1â2, 28 January 2005, Pages 139-143
Journal: Applied Catalysis A: General - Volume 279, Issues 1â2, 28 January 2005, Pages 139-143
نویسندگان
Qinghai Cai, Jing Li, Fuxing Bao, Yongkui Shan,