کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9610323 | 47172 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Nanostructured metal films: Fabrication and catalytic properties
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Thin nanostructured films consisting of monodispersive and amorphous Cu, Ni, or Pd nanoparticles were prepared by means of laser electrodispersion technique. These films were deposited on dielectric (thermally oxidized silicon) or semiconductor (naturally oxidized Si) supports, and the resulting particle surface density was closely controlled by the time of deposition. The nanoparticle size was 5Â nm for Cu, 2.5Â nm for Ni, and 2Â nm for Pd. In all cases, the relative particle size dispersion was less than 10%. The most important common feature of the fabricated catalysts is their unusually high activity, which has been observed in several test reactions including chlorohydrocarbon conversions (Cu and Ni) and hydrogenation (Ni and Pd). The observed strong dependencies of the catalytic activity on the particle surface density and on the nature of the support clearly indicate that alongside with small particle size and their amorphous state, inter-particle interactions or particle interaction with the support play decisive role in determining the catalytic activity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 105, Issues 3â4, 15 August 2005, Pages 344-349
Journal: Catalysis Today - Volume 105, Issues 3â4, 15 August 2005, Pages 344-349
نویسندگان
T.N. Rostovshchikova, V.V. Smirnov, S.A. Gurevich, V.M. Kozhevin, D.A. Yavsin, S.M. Nevskaya, S.A. Nikolaev, E.S. Lokteva,