کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9610350 | 47172 | 2005 | 8 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Modelling of an SCR catalytic converter for diesel exhaust after treatment: Dynamic effects at low temperature
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Modelling of an SCR catalytic converter for diesel exhaust after treatment: Dynamic effects at low temperature Modelling of an SCR catalytic converter for diesel exhaust after treatment: Dynamic effects at low temperature](/preview/png/9610350.png)
چکیده انگلیسی
As part of a fundamental and applied work on the development of an unsteady mathematical model of the NH3-selective catalytic reduction (SCR) process for design and control of integrated after-treatment systems of heavy-duty engines, we present herein a transient kinetic analysis of the standard SCR NO + NH3 system which provides new insight in the catalytic kinetics and mechanism prevailing at low temperatures. Based on kinetic runs performed over a commercial powdered V2O5-WO3-TiO2 catalyst in the 175-450 °C T-range feeding NH3 and NO (1000 ppm) in the presence of H2O (1-10%, v/v) and O2 (2-6%, v/v), an original dual-site modified redox rate law is derived which effectively accounts for NH3 inhibition effects observed during transient reactive experiments at T < 250 °C. We also demonstrate that implementation of the novel modified redox kinetics into a fully predictive 1D + 1D model of SCR monolith reactors can significantly improve simulations of SCR transient runs at different scales, including engine test bench experiments over full-scale SCR honeycomb catalysts.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 105, Issues 3â4, 15 August 2005, Pages 529-536
Journal: Catalysis Today - Volume 105, Issues 3â4, 15 August 2005, Pages 529-536
نویسندگان
Enrico Tronconi, Isabella Nova, Cristian Ciardelli, Daniel Chatterjee, Brigitte Bandl-Konrad, Thomas Burkhardt,