کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9610378 | 47172 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Oxidative carbonylation of phenol over the mesoporous palladium-copper-oxide/silica catalyst prepared by sol-gel coupling with W/O microemulsion
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Oxidative carbonylation of phenol over the mesoporous palladium-copper-oxide/silica catalyst prepared by sol-gel coupling with W/O microemulsion Oxidative carbonylation of phenol over the mesoporous palladium-copper-oxide/silica catalyst prepared by sol-gel coupling with W/O microemulsion](/preview/png/9610378.png)
چکیده انگلیسی
A novel mesoporous catalyst Pd-Cu-O/SiO2 were prepared by sol-gel method coupling with W/O microemulsion for oxidative carbonylation of phenol to diphenyl carbonate (DPC). It has larger specific surface area, pore volume and rather narrow pore size distribution in the range of mesopore. The catalyst shows a comparatively good activity for the synthesis of DPC and the yield reaches to 20.3%, the turnover frequency (TOF) is 15.1 mol-DPC/mol-Pd h, at certain conditions. The less dispersed active centers and the diffusion resistance caused by the numerous pores influence the reaction negatively.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 105, Issues 3â4, 15 August 2005, Pages 724-728
Journal: Catalysis Today - Volume 105, Issues 3â4, 15 August 2005, Pages 724-728
نویسندگان
Wei Xue, Yanji Wang, Xinqiang Zhao,