کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9610546 | 47182 | 2005 | 12 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical promotion of catalysis: mechanistic investigations and monolithic electropromoted reactors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
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چکیده انگلیسی
Recent progress is surveyed both in elucidating the mechanism of electrochemical promotion at the molecular level and in utilizing it in monolithic electropromoted catalytic reactors. On the mechanistic side, recent 18O2 TPD and 18O2Â +Â CO TP reaction studies have confirmed, together with STM, the validity of the sacrificial promoter model for both electrochemical promotion and metal-support interactions of Pt and Rh with anionic (YSZ) and mixed anionic-electronic supports. On the practical side, two recent advances are discussed, i.e., the electropromotion of thin (40Â nm) sputtered catalyst films, with metal dispersion of the order of 20%, and the development of the monolithic electropromoted reactor (MEPR) which is a hybrid between a monolithic catalytic reactor and a flat-plate solid oxide fuel cell and allows for compact design and easy scale-up and scale-down of electropromoted catalytic units.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Catalysis Today - Volume 100, Issues 1â2, 15 February 2005, Pages 133-144
Journal: Catalysis Today - Volume 100, Issues 1â2, 15 February 2005, Pages 133-144
نویسندگان
D. Tsiplakides, S. Balomenou, A. Katsaounis, D. Archonta, C. Koutsodontis, C.G. Vayenas,