کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9635816 1427490 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Phase equilibrium behavior for hydrogenolysis components: three-phase equilibria LLV and retrograde behavior
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Phase equilibrium behavior for hydrogenolysis components: three-phase equilibria LLV and retrograde behavior
چکیده انگلیسی
Knowledge of the phase equilibria of the reaction mixture, and the boundaries of the homogeneous phase region are required in order to determine the most favorable operating conditions for supercritical hydrogenolysis. In the present work, the phase behavior of binary and ternary mixtures with methyl palmitate, hexadecanol, hydrogen and propane is analyzed. The range of temperatures covered was between 300 K and 450 K and of pressures up to 16 MPa. Three-phase liquid-liquid-vapor equilibria were found for the system hydrogen + propane + hexadecanol, with retrograde behavior of the lighter liquid.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: The Journal of Supercritical Fluids - Volume 34, Issue 2, June 2005, Pages 183-187
نویسندگان
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