کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9689943 | 1457042 | 2005 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Mg-Al layered double hydroxide intercalated with ethylene-diaminetetraacetate anion: Synthesis and application to the uptake of heavy metal ions from an aqueous solution
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
تصفیه و جداسازی
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چکیده انگلیسی
edta·Mg-Al LDH that had an edta anion intercalated in the interlayer of Mg-Al LDH, could be synthesized by adding a solution of Mg(NO3)2 and Al(NO3)3 to a solution of NaOH and edta-2Na (disodium dihydrogen edta dihydrate). The effect of the NaOH concentration in the solution on the formation of edta·Mg-Al LDH was examined to control the chemical species of the edta anion incorporated in the interlayer. The synthesized edta·Mg-Al LDH was found to have a capacity for rapid uptake of Cu2+ and Cd2+ from an aqueous solution at the constant pH of 5.0. This capacity is attributed to the formation of the edta-metal complex in the interlayer of edta·Mg-Al LDH. This paper reports that the concentration of Cu2+ decreased from 64 mg/l to less than the effluent standards in Japan (3 mg/l) due to the edta·Mg-Al LDH in a short span of 10 min. Furthermore, the concentration of Cd2+ decreased from 112 mg/l to less than 1 mg/l within 15 min. The Cu2+ was observed to be preferentially uptaken from a Cu-Cd mixed chloride solution by the edta·Mg-Al LDH at the pH of 5.0. The function of edta anions as chelating agents is considered to be adequately active in the interlayer of edta·Mg-Al LDH.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Separation and Purification Technology - Volume 47, Issues 1â2, December 2005, Pages 20-26
Journal: Separation and Purification Technology - Volume 47, Issues 1â2, December 2005, Pages 20-26
نویسندگان
Tomohito Kameda, Shingo Saito, Yoshiaki Umetsu,