Intrinsic compensation phenomenon in thermally stimulated depolarisation studies

The compensation behaviour as observed in thermally stimulated depolarisation currents (TSDC) corresponds to the linear relationship found between the Arrhenius (or Eyring) apparent thermokinetic parameters obtained in a series of thermal sampling (TS) experiments performed in the region of cooperative relaxation processes, particularly around the glass transition of glass forming materials. The compensation effect exhibits the same features of the intrinsic compensation found for any given TS curve, where the values of Ea and τ0, in the region where the sum of square residues is low, are highly correlated, being this correlation similar to the conventional compensation. This intrinsic compensation is a result, and exhibits the same features, of the compensation found in the description of a given set of points obtained with the Arrhenius equation with the own Arrhenius equation. This compensation is transmitted directly to the equation that describes the temperature dependence of the depolarisation currents, J(T), as a nearly direct relationship exists between J(T) and τ(T). In fact, it was shown that J(T) for an elementary process could be approximated by P0 exp[−c/τ(T)]/τ(T), c being a constant.