کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9776260 1509483 2005 4 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
New magnetic conductors and superconductors based on BEDT-TTF and BEDS-TTF
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد بیومتریال
پیش نمایش صفحه اول مقاله
New magnetic conductors and superconductors based on BEDT-TTF and BEDS-TTF
چکیده انگلیسی
Here we present our last results in the search for multifunctionality in conducting molecular materials obtained by combining paramagnetic molecular complexes with organic donors to produce paramagnetic molecular metals and superconductors. The structural and physical characterization of two new molecular paramagnetic superconductors ET4[H3OM(C2O4)3].PhBr (MIII = Cr and Fe) are presented (ET = BEDT-TTF = bis(ethylenedithio)tetrathiafulvalene). These salts present a superconductor transition at Tc = 1.5 and 4.0 K, respectively and very anisotropic critical fields Hc2a ≈ Hc2b ≈0.5 T and HC2C ≈ 8 T for the Fe derivative. We will also present the structural and physical characterization of two new metallic paramagnetic systems: ET4[H3OM(C2O4)3].PhCl (M = CrIII and FeIII) and five different new semiconducting paramagnets obtained with the donor bis(ethylenediselena)tetrathiafulvalene (BEDS-TTF = BEST) and [M(C2O4)3]3− (M = CrIII and FeIII) complexes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 154, Issues 1–3, 22 September 2005, Pages 245-248
نویسندگان
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