کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9776487 | 1509486 | 2005 | 13 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
AOT reverse micelle, a new organized medium for the electrosynthesis of polyaromatic hydrocarbons; application to the electropolymerization of biphenyl
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
بیومتریال
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: AOT reverse micelle, a new organized medium for the electrosynthesis of polyaromatic hydrocarbons; application to the electropolymerization of biphenyl AOT reverse micelle, a new organized medium for the electrosynthesis of polyaromatic hydrocarbons; application to the electropolymerization of biphenyl](/preview/png/9776487.png)
چکیده انگلیسی
Electrosynthesis of poly(biphenyl) (PBP) films was performed in an AOT [sodium bis(2-ethylhexyl) sulfosuccinate] reverse micelle by cyclic voltammetry and chronopotentiometry on a platinum electrode. An electroactive PBP film was formed either by cyclic voltammetry between â0.6 and 1.65 V/Ag/AgCl or under current control (j = 0.2 mA/cm2). PBP films were characterized electrochemically and spectroscopically (MALDI-TOF mass spectrometry), NMR, Raman, FT-IR, X-ray photoelectron and UV-vis spectroscopy). The structure of the PBP films involved sequences of ramified trimer possessing quinoid forms. This type of sequences can give strongly condensed oligomers with PBP molar mass up to 2669.6 g/mol according to the electrosynthesis charge.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Synthetic Metals - Volume 150, Issue 3, 10 May 2005, Pages 227-239
Journal: Synthetic Metals - Volume 150, Issue 3, 10 May 2005, Pages 227-239
نویسندگان
A. Koné, M.M. Dieng, J.-J. Aaron, M. Lazerges, M. Jouini, S. Aeiyach, P.C. Lacaze,