کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9781799 | 1511637 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Electrochemical behaviors of PuN and (U, Pu)N in LiCl-KCl eutectic melts
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
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چکیده انگلیسی
Electrochemical behaviors of PuN and (U, Pu)N in the LiCl-KCl eutectic melts at 773 K were investigated by cyclic voltammetry. The electrochemical dissolution of PuN and (U, Pu)N began nearly at â0.90±0.05 and â0.95±0.05 V (vs. Ag+/Ag), respectively. The rest potentials of PuN and (U, Pu)N were observed at about 0.15 V more negative potential than that of UN, in the present experimental condition. The observed rest potentials of (U, Pu)N depended on the equilibrium potential of the Pu3+/PuN. In the cyclic voltammogram measured by use of (U, Pu)N as the working electrode, a steep rise of the positive current was observed at potentials more positive than â0.45 V in analogy with the cyclic voltammogram measured by use of UN as the working electrode. These indicate that UN and PuN in (U, Pu)N would be dissolved independently irrespective of forming the solid solution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 66, Issues 2â4, FebruaryâApril 2005, Pages 456-460
Journal: Journal of Physics and Chemistry of Solids - Volume 66, Issues 2â4, FebruaryâApril 2005, Pages 456-460
نویسندگان
O. Shirai, T. Kato, T. Iwai, Y. Arai, T. Yamashita,