کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
9781799 1511637 2005 5 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Electrochemical behaviors of PuN and (U, Pu)N in LiCl-KCl eutectic melts
موضوعات مرتبط
مهندسی و علوم پایه مهندسی مواد مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
Electrochemical behaviors of PuN and (U, Pu)N in LiCl-KCl eutectic melts
چکیده انگلیسی
Electrochemical behaviors of PuN and (U, Pu)N in the LiCl-KCl eutectic melts at 773 K were investigated by cyclic voltammetry. The electrochemical dissolution of PuN and (U, Pu)N began nearly at −0.90±0.05 and −0.95±0.05 V (vs. Ag+/Ag), respectively. The rest potentials of PuN and (U, Pu)N were observed at about 0.15 V more negative potential than that of UN, in the present experimental condition. The observed rest potentials of (U, Pu)N depended on the equilibrium potential of the Pu3+/PuN. In the cyclic voltammogram measured by use of (U, Pu)N as the working electrode, a steep rise of the positive current was observed at potentials more positive than −0.45 V in analogy with the cyclic voltammogram measured by use of UN as the working electrode. These indicate that UN and PuN in (U, Pu)N would be dissolved independently irrespective of forming the solid solution.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Physics and Chemistry of Solids - Volume 66, Issues 2–4, February–April 2005, Pages 456-460
نویسندگان
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