کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9782984 | 1511867 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
α-Pinene conversion by modified-kaolinitic clay
دانلود مقاله + سفارش ترجمه
دانلود مقاله ISI انگلیسی
رایگان برای ایرانیان
کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The isomerization of α-pinene using natural kaolinitic clay before and after different treatments was studied in this work. The kaolinite is a clay material constituted by phyllosilicate 1:1 layer (one sheet of tetrahedral silicon and one sheet of octahedral alumina). The clay was treated at different times using 6.0 N solution of sulfuric acid previous heating to 500 or 700 K. The materials were characterized by X-ray diffraction, by chemical analyses and acidity measurements. The catalytic reactions were carried out at 373 K in a reactor batch with condenser and stirrer. Samples were taken at regular intervals, and reactants and products were quantitatively analyzed with a gas chromatograph after separation of the individual compounds. Conversions of alpha pinene between 67 and 94%, and selectivities in camphene and in limonene of 65 and 23%, respectively, were obtained with the clay treated at different conditions. The structural and textural changes of the clay by the treatments influenced on catalytic reactions.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 93, Issues 2â3, 15 October 2005, Pages 296-300
Journal: Materials Chemistry and Physics - Volume 93, Issues 2â3, 15 October 2005, Pages 296-300
نویسندگان
C. Volzone, O. Masini, N.A. Comelli, L.M. Grzona, E.N. Ponzi, M.I. Ponzi,