کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9783060 | 1511868 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Correlation between photoreactivity and photophysics of sulfated TiO2 photocatalyst
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
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چکیده انگلیسی
The sulfated TiO2 were prepared by dipping TiO2 in H2SO4 solutions. The reactivity of methylene blue photocatalytic degradation of all SO42â/TiO2 are higher than that of TiO2, and the optimum molar concentration of SO42â on TiO2 is 9%. IR confirmed that the chelating bidentate SO42â and unidentate SO42â coexist in SO42â/TiO2. Methylene blue is cationic dye. Maybe the Lewis acid and Bronsted acid coexist in the SO42â/TiO2 catalyst, the adsorption of methylene blue on the catalyst increases. The high photocatalytic reactivity of SO42â/TiO2 is consistent with the good adsorption. The presence of SO42â enhances the light absorption in the visible region of SO42â/TiO2, and the photocatalytic activity of SO42â/TiO2 correlates with reflectance of the samples in the visible light region. The fluorescence spectra show that weaker the fluorescence intensity the higher the activity. Thus, The enhanced photocatalytic activity of SO42â/TiO2 may be explained by the good adsorption of methylene blue on the catalysts, high light absorption in the visible region, and weak fluorescence intensity.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 92, Issues 2â3, 15 August 2005, Pages 470-474
Journal: Materials Chemistry and Physics - Volume 92, Issues 2â3, 15 August 2005, Pages 470-474
نویسندگان
Yue-Hua Xu, Liang-Yan Wang, Qi Zhang, Shao-Jian Zheng, Xin-Jun Li, Cong Huang,