کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9783112 | 1511869 | 2005 | 6 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Corrosion behavior of aluminium in ethyleneglycol-water electrolytes containing EDTA
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
مواد الکترونیکی، نوری و مغناطیسی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The role of EDTA on the behavior of Al in ethyleneglycol-water media has been investigated through electrochemical and atomic force microscopy measurements. It has been found that, at open circuit potential (OCP), as compared to an aqueous solution of the same pH, the adsorption of EDTA on the surface of the Al electrode is favored in ethyleneglycol rich mixtures. In these solutions, the defects of the aluminium oxide film are repaired due to the adsorption of the ligand, giving rise to a more protective layer. Moreover, as compared to the oxide film grown in the absence of EDTA, the one grown in its presence shows greater uniformity and lesser porosity, remaining stable for longer immersion periods.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Materials Chemistry and Physics - Volume 91, Issues 2â3, 15 June 2005, Pages 375-380
Journal: Materials Chemistry and Physics - Volume 91, Issues 2â3, 15 June 2005, Pages 375-380
نویسندگان
L.R.B. Holzle, D.S. Azambuja, C.M.S. Piatnicki, G.E. Englert,