کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
9801919 | 1515734 | 2005 | 5 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Pressure-induced phase transformation in controlled shape ZnO nanorods
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی مواد
دانش مواد (عمومی)
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
We present an in situ energy-dispersive X-ray diffraction study of pressure-induced phase transformations in ZnO nanorods and the corresponding bulk material up to 35.0Â GPa at room temperature. ZnO nanorods with the wurtzite (P63mc) structure start to transform to a rocksalt (Fm3m) structure at a pressure of 8.0Â GPa, a pressure appreciably higher than the value observed for the bulk material (7.0Â GPa). This behavior suggests that both the volume collapse and the surface energy difference between the phases involved mainly govern the change of the transition pressure. The reduction of the particle size for ZnO crystallites leads to a significant increase of the bulk modulus (B0) and the pressure range of the coexistence of the wurtzite and rocksalt phases suggest that hardness of ZnO nanorods is higher than ZnO bulk.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Solid State Communications - Volume 135, Issues 11â12, September 2005, Pages 780-784
Journal: Solid State Communications - Volume 135, Issues 11â12, September 2005, Pages 780-784
نویسندگان
Xiang Wu, Ziyu Wu, Lin Guo, Chenmin Liu, Jing Liu, Xiaodong Li, Huibin Xu,