Keywords: Cp; η5-cyclopentadienyl; Cp*; η5-pentamethylcyclopentadienyl; Cy; cyclohexyl; DFT; density functional theory; DMAP; 4-(dimethylamino)pyridine; DME; 1,2-dimethoxyethane; dmpe; 1,2-bis(dimethylphosphino)ethane; dppe; 1,2-bis(diphenylphosphino)ethane; Eind
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Keywords: Acac; acetylacetone; Ar; aryl; BDPP; 2,4-bis(diphenylphosphino)pentane; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; BINOL; 1,1â²-bi-2-naphthol; Bn; benzyl; Boc; tert-butoxycarbonyl; Bz; benzoyl; Cbz; benzyloxycarbonyl; Cy; cyclohexyl; DCE; 1,
Lanthanide phosphine oxide complexes
Keywords: Acac; acetylacetonate; Bu; butyl; iBi; isobutyl; tBu; tertiary butyl; Bz; benzyl; CMPO; carbamoylmethylphosphine oxide; Cp; cyclopentadienyl; Cy; cyclohexyl; DMF; dimethylformamide; DMSO; dimethylsulfoxide; Et; ethyl; EXASF; Extended X-ray Absorption Fine
Keywords: DMSO; dimethylsulphoxide; TD-DFT; time-dependent density functional theory; ILCT; intraligand charge transfer; TRIR; time-resolved infra-red; LLCT; interligand charge transfer; THF; tetrahydrofuran; Bn; benzyl; Ph; phenyl; dfppyH; 2-(2,4-difluorophenyl)py
Keywords: Ac; acetyl; An; anisyl; Ar; aryl; ATP; adenosine triphosphate; Bn; benzyl; Boc; tert-butoxycarbonyl; Bu; butyl; Bz; benzoyl; cat; catalyst; conv; conversion; Cy; cyclohexyl; DABCO; 1,4-diazabicyclo[2.2.2]octane; DBU; 1,8-diazabicyclo[5.4.0]undec-7-ene; de
Recent developments in enantioselective lanthanide-catalyzed transformations
Keywords: Ar; aryl; BINOL; 1,1â²-bi-2-naphthol; Bpy; 2,2â²-bipyridyl; Bn; benzyl; BNP; Binaphthophosphole; Boc; tert-butoxycarbonyl; BSA; bis-(trimethylsilyl)acetamide; CB; carbon black; cod; 1,5-cyclooctadiene; Cy; cyclohexyl; DBDMH; 1,3-dibromo-5,5-dimethylhyda
Coordination chemistry of 3- and 4-mercaptobenzoate ligands: Versatile hydrogen-bonding isomers of the thiosalicylate (2-mercaptobenzoate) ligand
Keywords: bipy; 2,2â²-bipyridine; Cy; cyclohexyl; DFT; density functional theory; DMF; N,N-dimethylformamide; DMSO; dimethylsulfoxide, Me2S(O); dppb; 1,4-bis(diphenylphosphino)butane, Ph2P(CH2)4PPh2; dppe; 1,2-bis(diphenylphosphino)ethane, Ph2P(CH2)2PPh2; dppp; 1,
Keywords: Nitro compounds; Natural products; Pharmaceuticals; Stereoselective synthesis; Organocatalysis; Metal catalysis; Nitronates; Nitrile oxides; AIBN; azobisisobutyronitrile; AZADO; 2-azaadamantane-N-oxyl; 9-BBN; 9-borabicyclo[3.3.1]nonane; BINAP; 2,2â²-bis(
Keywords: acac; acetylacetonate; All; allyl; An; methoxyphenyl; BARF; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; Bn; benzyl; Bu; n-butyl; Cp; η5-cyclopentadienyl; Cpâ²; η5-methylcyclopentadienyl; CPE; controlled potential electrolysis; CV; cyclic voltammetr
Keywords: Graphene; Cyclohexane; Cyclohexene; Cyclohexyl; Functionalization; Density functional theory;
Keywords: Triphenylanime; Cyclohexyl; Solvent-free reaction; Solvatochromic effect; High quantum yields; Picric acid detection
Sustainable metal complexes for organic light-emitting diodes (OLEDs)
Keywords: 3MLCT; triplet metal-ligand charge transfer; 4MTPD; N,Nâ²-diphenyl-N,Nâ²-(3-methyl)-1,1â²-biphenyl-4,4â²-diamine; acac; acetylacetonate; AIEE; aggregation induced enhanced emission; An; (ortho)-anisyl; BAlq; bis(2-methyl-8-quninolinato)-4-phenylphen
Transition-metal-catalyzed transfer carbonylation with HCOOH or HCHO as non-gaseous C1 source
Keywords: Ar; aryl; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; BIPHEP; 2,2â²-bis(diphenylphosphino)-1,1â²-biphenyl; BMIMCl; 1-butyl-3-methylimidazolium chloride; C1; one carbon; CO; carbon monoxide; COD; cycloocta-1,5-diene; CO2; carbon dioxide; Cy;
Activation of alkynes by diphosphine- and µ-phosphido-spanned heterobimetallic complexes
Keywords: COD; cyclooctadiene; Cp; cyclopentadienyl; Cp*; pentamethylcyclopentadienyl; Cy; cyclohexyl; DFT; density functional theory; dppm; bis(diphenylphosphino)methane; dppa; bis(diphenylphosphino)amine; dppe; bis(diphenylphosphino)ethane; DMAD; dimethyl acetyle
Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis
Keywords: δ; Chemical shift; 1D; One dimension; 2D; Two dimensions; Ac; Acetate; Acac; Acetylacetonate; Ad; Adamantyl; Ar; Aryl; BARF; Tetrakis(3,5-di-trifluoromethylphenyl)borate); Bipy; 2,2â²-bipyridine; Bu; Butyl; Bn; Benzyl; COD; Cyclooctadiene; COE; Cyclooct
Recent advances in η2-disilene and η2-disilyne mononuclear transition metal complexes and related compounds
Keywords: 2-Ad; 2-adamantylidene; cod; 1,5-cyclooctadiene; Cp; η5-cyclopentadienyl; Cp*; η5-pentamethylcyclopentadienyl; Cy; cyclohexyl; dcpe; 1,2-bis(dicyclohexylphosphino)ethane; DCD; Dewar-Chatt-Duncanson; DFT; density functional theory; DMAP; 4-(dimethyla
Achievement of regioselectivity in transition metal-catalyzed direct C-H (hetero)arylation reactions of heteroarenes with one heteroatom through the use of removable protecting/blocking substituents or traceless directing groups
Keywords: Chemoselectivity; Regioselectivity; Direct C-H (hetero)arylation; Transition metal catalysts; Removable groups; Traceless directing groups; Deprotection; Ac; acetyl; acac; acetylacetonate; 1-Ad; 1-adamantyl; AIBN; azobisisobutyronitrile; Ar; aryl; Boc;
Neutral tris(azolyl)phosphanes: An intriguing class of molecules in chemistry
Keywords: acac; acetylacetonate; acacF6; hexafluoro acetylacetonate; AIBN; azobisisobutyronitrile; APH; aminophenol; Az; azole; CA; carbonic anhydrase; CatH2; catechol; CH2C6H5; benzyl; Cp; cyclopentadienyl; Cy; cyclohexyl; cym; cymene; DIBQ; o-diiminobenzoquinone;
Persistence assessment of cyclohexyl- and norbornyl-derived ketones and their degradation products in different OECD screening tests
Keywords: Biodegradation; Cyclohexyl; Norbornyl; Ketone; Pathway prediction; Fragrance;
Beyond Triphos - New hinges for a classical chelating ligand
Keywords: Râ²EP3R; in general structures with general formula Râ²E(CH2PR2)3; AACVD; aerosol-assisted chemical vapour deposition; acac; acetylacetone; ATRA; atom-transfer radical additions; ATRP; atom-transfer radical polymerization; cod; 1,5-cyclooctadiene; Cpâ
Tetrahedron report number 967Asymmetric organocatalytic cycloadditions
Keywords: Ac; acetyl; Ad; adamantyl; Ar; aryl; BINAM; 1,1â²-binaphthalenyl-2,2â²-diamine; BINOL; 1,1â²-bi-2-naphthol; Bn; benzyl; Boc; tert-butoxycarbonyl; Bu; butyl; Bz; benzoyl; Cbz; benzyloxycarbonyl; Cy; cyclohexyl; DABCO; 1,4-diazabicyclo[2.2.2]octane; DDQ;
Tetrahedron report number 994β-Elimination competitions leading to CC bonds from alkylpalladium intermediates
Keywords: Palladium; Elimination; Heterocyclisation; Heck reaction; Wacker reaction; Aza-Wacker reaction; Selectivity; Atm; atmosphere; Boc; t-butoxycarbonyl; cat; catalytic; COD; 1,5-cyclooctadiene; Cy; cyclohexyl; dba; dibenzylidene acetone; DMA; N,N-dimethylacet
Recent developments in dynamic kinetic resolution
Keywords: Ac; acetyl; AIBN; 2,2â²-azobisisobutyronitrile; Ar; aryl; Atm; atmosphere; BARF; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; BINAP; 2,2â²-bis(diphenylphosphanyl)-1,1â²-binaphthyl; BINOL; 1,1â²-bi-2-naphthol; BIPHEP; 2,2â²-bis(diphenylphosphino)-1
Evaluation of new leptin fragments on food intake and body weight of normal rats
Keywords: 2-Cl-Z; 2-chloro-benzyloxycarbonyl; AAA; amino acid analysis; BOP; benzotriazol-1-yl-oxy-tris(dimethylamino) phosphonium hexafluorophosphate; Bzl; benzyl; CD; circular dichroism; CH3CN; acetonitrile; CHO; Formyl; CSF; Cerebrospinal fluid; DCM; dichloromet
Cycloaddition of oxidopyrylium species in organic synthesis
Keywords: Ac; Acetyl; acac; acetylacetonyl; Bn; benzyl; Bz; benzoyl; COD; cycloocta-1,5-diene; Cp; cyclopentadienyl; m-CPBA; m-chloroperbenzoic acid; Cy; cyclohexyl; DBN; 1,5-diazabicyclo[4.3.0]non-5-ene; DBU; 1,8-diazabicyclo[5.4.0]undec-7-ene; DMAD; dimethyl acet
Glycosulfoxides in carbohydrate chemistry
Keywords: Ac; acetyl; AIBN; (E)-2,2â²-azobis(2-methylpropionitrile), NCCMe2N=NCMe2CN; All; allyl; aq; aqueous; Bn; benzyl; BSNPO; 2-benzenesulfonyl-3-(m-nitrophenyl)oxaziridine; Bu; butyl; Bz; benzoyl; CD; cyclodextrin; Cy; cyclohexyl; DCM; dichloromethane; DFT; d
Gold-catalysed reactions of alcohols: isomerisation, inter- and intramolecular reactions leading to C-C and C-heteroatom bonds
Keywords: Gold; Alcohols; Catalysis; Rearrangement; Cyclisation; aq; aqueous; bmim; 1-butyl-3-methylimidazolium; Bn; benzyl; cat.; catalytic; Cy; cyclohexyl; DBU; 1,8-diazabicyclo[5.4.0]undec-7-ene; de; diastereoisomeric excess; dr; diastereoisomeric ratio; ee; ena
Asymmetric organocatalysis
Keywords: Ac; acetyl; Ar; aryl; BINOL; 1,1â²-bi-2-naphthol; Bn; benzyl; Boc; tert-butoxycarbonyl; Bu; butyl; Bz; benzoyl; Cbz; benzyloxycarbonyl; CPME; cyclopentyl methyl ether; Cy; cyclohexyl; DABCO; 1,4-diazabicyclo[2.2.2]octane; DBAB; dibenzylazodicarboxylate;
Recent developments in the synthesis of oxepines
Keywords: CAN; ceric ammonium nitrate; Cy; cyclohexyl; dba; dibenzylideneacetone; DBU; 1,8-diazabicyclo[5.4.0]undec-7-ene; DEAD; diethyl azodicarboxylate; DMAP; N,N-4-dimethylaminopyridine; DMDO; dimethyldioxirane; Eu(fod)3; europium 6,6,7,7,8,8,8-heptafluoro-2,2-d
Recent approaches to the construction of 1-azaspiro[4.5]decanes and related 1-azaspirocycles
Keywords: Azaspirocyclic ring systems; Spirocycles; 3° Carbon center; Ac; acetyl; AIBN; azobisisobutyronitrile(2,2â²-azo(2-methylpropionitrile)); Ar; aryl; Bn; benzyl; Boc; t-butoxycarbonyl; Bu; butyl; Cbz; benzyloxycarbonyl; Cy; cyclohexyl; DBB; di-t-butylbiphen
Recent advances in the chemistry of macroline, sarpagine and ajmaline-related indole alkaloids
Keywords: Ac; acetyl; AD; asymmetric dihydroxylation; AIBN; 2,2â²-azobisisobutyronitrile; Ar; aryl; 9-BBN; 9-borabicyclo[3.3.1]nonane; Bn; benzyl; Boc; tert-butoxycarbonyl; Bu; butyl; Bz; benzoyl; cat; catalytic; CBz; benzyloxycarbonyl; CLB; chlorobenzoyl; Cy; cyc
Use of chiral sulfoxides in asymmetric synthesis
Keywords: Ac; acetyl; Acac; acetylacetone; AIBN; 2,2â²-azobisisobutyronitrile; Ar; aryl; BF3·Et2O; boron trifluoride etherate; BINAP; 2,2â²-bis(diphenylphosphanyl)-1,1â²-binaphthyl; Bn; benzyl; Boc; tert-butoxycarbonyl; Born; borneol; Bu; butyl; Cbz; benzyloxyc
Some general principles for designing electrocatalysts with hydrogenase activity
Keywords: app.; apparent; bipy; bipyridine; buS42â; 1,2-bis(2-mercapto-3,5-di-t-butylphenylthio)ethane dianion; CB; conduction band; Cpâ; cyclopentadienyl anion; Cp*â; pentamethylcyclopentadienyl anion; Cy; cyclohexyl; cyclam; 1,4,8,11-tetraazacyclotetradecan
Metal derivatives of poly(pyrazolyl)alkanes
Keywords: Metal derivatives; Poly(pyrazolyl)alkanes; Tris(pyrazolyl)alkanes; [9]aneS3; 1,4,7-trithiacyclononane; Ar; aryl; Bipy; 2,2â²-bipyridyl; bn; benzyl; nBu; n-butyl; tBu; tert-butyl; Cp; cyclopentadienyl; Cpâ; pentamethylcyclopentadienyl; cy; cyclohexyl; C
Metal derivatives of poly(pyrazolyl)alkanes
Keywords: acacH; 2,4-pentanedione; OAc; acetate; Bipy; 2,2â²-bipyridyl; Bn; benzyl; Bpx; a generical bis(pyrazolyl)borate; iBu; iso-butyl; nBu; normal-butyl; tBu; terz-butyl; camphpzH; 7,8,8-trimethyl-4,5,6,7-tetrahydromethano-2-indazole; COD; 1,5-cyclooctadiene;
Palladium-catalysed reactions of alcohols. Part B: Formation of C-C and C-N bonds from unsaturated alcohols
Keywords: Palladium; Alcohols; Arylation; Vinylation; Amination; η3-Allylpalladium; Umpolung; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; bmim; 1-n-butyl-3-methylimidazolium; Cy; cyclohexyl; cat.; catalytic; conv.; conversion; dba; dibenzylidene aceton
Recent developments in the Nazarov process
Keywords: Nazarov cyclisation; Divinyl ketone; Electrocyclisation; Cyclopentenone; Ar; aryl; BF3·Et2O; boron trifluoride etherate; Boc; tert-butoxycarbonyl; Bu; butyl; Cbz; benzyloxycarbonyl; Chx; cyclohexyl; Cp; cyclopentadienyl; DIB; o-diiodobenzene; Dppe; bis(d
Palladium-catalysed reactions of alcohols. Part D: Rearrangements, carbonylations, carboxylations and miscellaneous reactions
Keywords: Palladium; Catalysis; Alcohols; Rearrangement; Cleavages; Carbonylations; Carboxylations; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; cat.; catalytic; conv.; conversion; dba; dibenzylidene acetone; de; diastereoisomeric excess; ee; enantiomeri
Palladium-catalysed reactions of alcohols. Part C: Formation of ether linkages
Keywords: Palladium; Alcohols; Etherification; Heterocyclisation; Oxypalladation; η3-Allylpalladium; atm; atmosphere; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; cat.; catalytic; COD; 1,5-cyclooctadiene; conv; conversion; Cy; cyclohexyl; dba; dibenzyli
Non-conventional methodologies for transition-metal catalysed carbon-carbon coupling: a critical overview. Part 1: The Heck reaction
Keywords: Heck reaction; Supercritical fluids; Ionic liquids; Fluorous media; Aqueous solvents; Microwave; Ultrasound; High pressure; Nanofiltration; Microreactors; Ball-milling conditions; A; ampere; AAEMA; deprotonated form of 2-(acetoacetoxy)ethyl methacrylate;