Keywords: Oxindole; Alkene; Difluoromethylation; Phosphonium salt; Photoredox catalysis;
مقالات ISI (ترجمه نشده)
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Keywords: Nickel catalysis; Cross coupling reaction; High-throughput experimentation; Difluoromethylation;
Decarboxylative nucleophilic difluoromethylation of aldehydes and imines
Keywords: Decarboxylative; Nucleophilic; Difluoromethylation; Aldehydes; Imines;
Nucleophilic difluoromethylation of aromatic aldehydes using trimethyl(trifluoromethyl)silane (TMSCF3)
Keywords: Difluoromethylation; Aromatic aldehydes; TMSCF3; Lithium iodide; Ruppert-Prakash reagent; Lithium tetrafluoroborate;
Recent advances in carbon-difluoroalkylation and -difluoroolefination with difluorocarbene
Keywords: Difluoromethylation; Difluoroolefination; CF2 carbene; Fluoroalkylation;
Difluoromethylation of parent azoles
Keywords: Pyrrole; 1,2,3-Triazole; 1,2,4-Triazole; Tetrazole; Difluoromethylation;
Visible light photoredox-catalyzed difluoromethylation and ring expansion of 1-(1-arylvinyl)cyclobutanols
Keywords: Difluoromethylation; Photoredox reaction; Radical process; 1,2-Migration; Difluoromethyl-substituted cyclopentanones;
A convenient, transition metal-free synthesis of difluoromethyl selenoethers from organic selenocyanates and TMSCF2H
Keywords: Difluoromethyl selenoether; Transition metal-free; Selenocyanate; Difluoromethylselenol; Difluoromethylation;
Copper-catalyzed allylic difluoromethylation of allyl carbonates with (difluoromethyl)zinc reagent
Keywords: Organofluorine chemistry; Bioisosteric effect; Difluoromethyl group; Difluoromethylation; Allylic substitution;
Efficient nucleophilic difluoromethylation of aldehydes with (phenylsulfonyl)difluoromethylzinc and (phenylsulfonyl)difluoromethylcadmium reagents
Keywords: Difluoromethylation; Sulfone; Aldehyde; Organozinc reagent; Organocadmium reagent;
Solvent-controlled difluoromethylation of 2′-hydroxychalcones for divergent synthesis of 2′-difluoromethoxychalcones and 2,2-difluoro-3-styryl-2,3-dihydrobenzofuran-3-ols
Keywords: Difluoromethylation; Difluorocarbene; Solvent-controlled reaction; Cyclization
Organocatalytic, difluorocarbene-based S-difluoromethylation of thiocarbonyl compounds
Keywords: Difluorocarbene; Difluoromethylation; Organocatalyst; Sulfur; Thioamide; Thiocarbamate
Nucleophilic addition of (difluoromethyl)trimethylsilane to selected α-imino ketones and aryl diketones
Keywords: (Difluoromethyl)trimethylsilane; α-Imino ketones; Diketones; Difluoromethylation; β-Amino alcohols; 1,2-Diols;
Direct S-difluoromethylation of thiols using the Ruppert-Prakash reagent
Keywords: Ruppert-Prakash reagent; TMSCF3; Difluoromethylation; Thiols; Siladifluoromethylation; Difluoromethyl thioethers; Nucleophilic (arylsulfanyl)difluoromethylation; RSCF2H; RSCF2TMS;
Use of fluoroform as a source of difluorocarbene in the synthesis of N-CF2H heterocycles and difluoromethoxypyridines
Keywords: Fluoroform; Difluoromethylation; Difluorocarbene; Difluoromethoxy group
Radical (2-pyridylsulfonyl)difluoromethylation of terminal alkenes with iododifluoromethyl 2-pyridyl sulfone
Keywords: Radical reactions; (2-Pyridylsulfonyl)difluoromethylation; Triethylborane; Iododifluoromethyl 2-pyridyl sulfone; Difluoromethylation;
Difluoromethylation and trifluoromethylation reagents derived from tetrafluoroethane β-sultone: Synthesis, reactivity and applications
Keywords: Tetrafluoroethane β-sultone; Difluoromethylation; Trifluoromethylation; Fluorine; Reagents; Derivatives
Nucleophilic difluoro(phenylsulfonyl)methylation of carbonyls with PhSO2CF2H reagent in the presence of in situ generated substoichiometric amount of base
Keywords: (Phenylsulfonyl)difluoromethylation; Difluoromethylation; Nucleophilic fluoroalkylation; Hydrofluorocarbons; Aldehydes; Alcohols;
Regioselective nucleophilic addition of 3-aryl-5-difluoromethyl-isoxazoles to aldehydes
Keywords: Difluoromethylation; Regioselectivity; Nucleophilic addition reaction; Isoxazole
Nucleophilic difluoromethylation of N,N-acetals with TMSCF2SO2Ph reagent promoted by trifluoroacetic acid: A facile access to α-difluoromethylated tertiary amines
Keywords: (Phenylsulfonyl)difluoromethylation; Difluoromethylation; Nucleophilic fluoroalkylation; N,N-acetals; Amines
NHC-catalyzed generation of difluorocarbene and its application to difluoromethylation of oxygen nucleophiles
Keywords: Difluorocarbene; NHC; Difluoromethylation; Organocatalyst; Difluoromethyl ethers; Difluoromethyl imidates
Difluoro(phenylchalcogen)methylation of aldehydes, ketones, and imines with S-, Se-, and Te-containing reagents PhXCF2H (X = S, Se, Te)
Keywords: (Phenylchalcogen)difluoromethylation; Fluorine; Difluoromethylation; Nucleophilic fluoroalkylation; Diastereoselectivity
Chlorodifluoromethyl aryl ketones and sulfones as difluorocarbene reagents: The substituent effect
Keywords: Difluorocarbene; Difluoromethylation; Chlorodifluoromethyl ketone; Chlorodifluoromethyl sulfone; Substituent effect
Diethyl bromodifluoromethylphosphonate: a highly efficient and environmentally benign difluorocarbene precursor
Keywords: Difluorocarbene; Diethyl bromodifluoromethylphosphonate; Difluoromethylation;
Fluoride ion-mediated nucleophilic fluoroalkylation of alkyl halides with Me3SiCF2SPh: Synthesis of PhSCF2- and CF2H-containing compounds
Keywords: (Phenylthio)difluoromethylation; Difluoromethylation; Selective fluoroalkylation; Nucleophilic substitution; Alkyl halides
Stereoselective synthesis of α-difluoromethyl-β-amino alcohols via nucleophilic difluoromethylation with Me3SiCF2SO2Ph
Keywords: Fluorine; Difluoromethylation; Amino alcohol; Stereoselective;
Nucleophilic difluoromethylation and difluoromethylenation of aldehydes and ketones using diethyl difluoromethylphosphonate
Keywords: Difluoromethylation; Difluoromethylenation; Phosphonate; Nucleophilic addition;
Synthesis and evaluation of new difluoromethyl azoles as antileishmanial agents
Keywords: Antileishmanial activity; Difluoromethylation; Imidazole; 1,2,3-Triazole
Reactions of aliphatic fluoro-alcohols with CHClF2 at atmospheric pressure
Keywords: Difluoromethylation; Difluorocarbene; Chlorodifluoromethane; Fluorinated ether
Synthesis, tuberculosis inhibitory activity, and SAR study of N-substituted-phenyl-1,2,3-triazole derivatives
Keywords: Tuberculosis; Diazomalonaldehyde; 1,2,3-Triazoles; Difluoromethylation; DAST
Nucleophilic difluoromethylation of carbonyl compounds using TMSCF2SO2Ph and Mg0-mediated desulfonylation
Keywords: Difluoromethylation; Fluorine; Magnesium; Desulfonylation;