Keywords: فعال سازی دی اکسیژن; Tris-copper centers; Ligand design; Dioxygen activation; Phosphate esters hydrolysis;
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Small-molecule models of tyrosinase: From ligand hydroxylation to catalytic monooxygenation of external substrates
Keywords: فعال سازی دی اکسیژن; BIMZ; bis(1-methylimidazol-2-yl)methane; BPM; 1,1â²-methylenebis-1H-pyrazole; CO; catechol oxidase; CT; charge transfer; dmBPM; 1,1â²-methylenebis(3,5-di-methyl-1H-pyrazole; DFT; density functional theory; l-DOPA; 3,4-dihydroxy-l-phenylalanine; 2,4-DTBP
Dioxygen activation chemistry by synthetic mononuclear nonheme iron, copper and chromium complexes
Keywords: فعال سازی دی اکسیژن; Metalloenzymes; Biomimetics; Dioxygen activation; Metal-oxygen intermediate; Nonheme models;
Keywords: فعال سازی دی اکسیژن; RR; resonance Raman; IR; infrared; UV-Vis; ultraviolet-visible; EPR; electron paramagnetic resonance; EXAFS; extended X-ray absorption fine structure; NRVS; nuclear resonance vibrational spectroscopy; DFT; density functional theory; NOS; nitric oxide
Keywords: فعال سازی دی اکسیژن; 15-cyclam; 1,4,8,12-tetraazacyclopentadecane; 15-TMC; 1,4,8,12-tetramethyl-1,4,8,12-tetraazacyclopentadecane; 6-MeTPA; (6-methyl-2-pyridylmethyl)bis(2-pyridylmethyl)amine; 6-Me3TPA; tris(6-methyl-2-pyridylmethyl)amine; BisPi1; 2,4-(2-pyridyl)-3-(2-pyridyl
A monomeric manganese(II) catecholato complex: Synthesis, crystal structure, and reactivity toward molecular oxygen
Keywords: فعال سازی دی اکسیژن; Manganese complex; Hydrotris(pyrazolyl)borate; Catecholato ligand; Dioxygen activation; Catechol dioxygenase;
From model compounds to applications: Kinetic studies on the activation of dioxygen using an iron complex in a SuperFocus mixer
Keywords: فعال سازی دی اکسیژن; Dioxygen activation; Reusable reaction KIT system; Diiron peroxido complex; Kinetics; Stopped-flow; Continuous-flow;
Oxidation of acetaminophen by Green rust coupled with Cu(II) via dioxygen activation: The role of various interlayer anions (CO32â, SO42â, Clâ)
Keywords: فعال سازی دی اکسیژن; Green rust; Copper ions; Dioxygen activation; Interlayer anion;
Methanol oxidation on the Au(3â¯1â¯0) surface: A theoretical study
Keywords: فعال سازی دی اکسیژن; Heterogeneous catalysis; Gold; Nanoporous gold; Au(3â¯1â¯0); Stepped surface; Dioxygen activation; Methanol; Selective oxidation; Low-coordinated sites; DFT; Microkinetic modeling;
Dioxygen activation routes in Mars-van Krevelen redox cycles catalyzed by metal oxides
Keywords: فعال سازی دی اکسیژن; Oxidative dehydrogenation; Redox cycle; Oxidation catalysis; Dioxygen activation; Density functional theory; Polyoxometalate; Epoxidation;
2-(2-Pyridyl)ethylamine (Pye) ligands in copper(I)-dioxygen chemistry
Keywords: فعال سازی دی اکسیژن; Dioxygen activation; Copper complex of active-oxygen species; 2-(2-Pyridyl)ethylamine (Pye) ligand; (μ-η2:η2-Peroxido)dicopper(II) complex; Bis(μ-oxido)dicopper(III) complex; Mixed-valent bis(μ3-oxido)tricopper(II,II,III) complex; Mononuclear copper(
Non-redox metal ions promoted dehydrogenation of saturated C-C bond by a ruthenium catalyst with dioxygen activation
Keywords: فعال سازی دی اکسیژن; Dehydrogenation; Ruthenium complexes; Dioxygen activation; Mechanism study;
A growing family of O2 activating dinuclear iron enzymes with key catalytic diiron(III)-peroxo intermediates: Biological systems and chemical models
Keywords: فعال سازی دی اکسیژن; Diiron enzymes; Dioxygen activation; Peroxo intermediates; Chemical models
Catechol oxidase and phenoxazinone synthase: Biomimetic functional models and mechanistic studies
Keywords: فعال سازی دی اکسیژن; Dioxygen activation; Catechol oxidase; Phenoxazinone synthase; Metal complexes; Oxidative CC bond coupling; Catalytic promiscuity
Dioxygen activation at room temperature during controllable and highly efficient acetaldehyde-to-acetic acid oxidation using a simple iron(III)–acetonitrile complex
Keywords: فعال سازی دی اکسیژن; Dioxygen activation; Iron–oxygen complex; Acetaldehyde oxidation; Michaelis–Menten kinetics
Structure and function of atypically coordinated enzymatic mononuclear non-heme-Fe(II) centers
Keywords: فعال سازی دی اکسیژن; 1,3-bis(2-pyridylimino)isoindoline; ind; 2OH-1,3-Ph2PD; 2-hydroxy-1,3-diphenylpropanedione; 6-Ph2TPA; N,N-bis[(6-phenyl-2-pyridyl)methyl]-N-[(2-pyridyl)-methyl]amine; α-KG; α-ketoglutarate; acac; acetylacetone (2,4-pentanedione); ADO; cysteamine dioxyge
Ferrous–tetrapolyphosphate complex induced dioxygen activation for toxic organic pollutants degradation
Keywords: فعال سازی دی اکسیژن; Ferrous–tetrapolyphosphate complex; Dioxygen activation; Wet air oxidation; Toxic organic pollutants
Electrocatalytic oxidation of organic substrates with molecular oxygen using tetradentate ruthenium(III)-Schiff base complexes as catalysts
Keywords: فعال سازی دی اکسیژن; Ruthenium-Schiff base complexes; Catalysis; Electrocatalysis; Dioxygen activation; Epoxidation; Oxidation reaction
Asymmetry and steric hindrance in tripodal ligands: Reaching the limit for octahedral geometry with the newly synthesized [(6-bromo 2-pyridylmethyl) (6-fluoro 2-pyridylmethyl) (2-pyridylmethyl)] amine tripod in FeCl2 complexes
Keywords: فعال سازی دی اکسیژن; Halogen-substituted tris(2-pyridylmethyl)amine ligands; Iron complexes; Tripodal tetramines; Asymmetry; Dioxygen activation
Active intermediates in heme monooxygenase reactions as revealed by cryoreduction/annealing, EPR/ENDOR studies
Keywords: فعال سازی دی اکسیژن; Cytochrome P450; Nitric oxide synthase; Heme oxygenase; ENDOR; EPR; Cryoreduction; Dioxygen activation
Cu-ZSM-5: A biomimetic inorganic model for methane oxidation
Keywords: فعال سازی دی اکسیژن; Zeolite; Cu-ZSM-5; Dioxygen activation; Dicopper(II)-oxo; Selective methane oxidation; Bio-inorganic mimicking; C–H activation
Evolution of strategies to prepare synthetic mimics of carboxylate-bridged diiron protein active sites
Keywords: فعال سازی دی اکسیژن; Carboxylate-bridged diiron modeling; Dioxygen activation; Biomimetic chemistry; Ligand design
Iron and cobalt complexes with the ligand (2-aminoethyl)bis(2-pyridylmethyl)amine (uns-penp) and derivatives
Keywords: فعال سازی دی اکسیژن; Iron complexes; Cobalt complexes; Tripodal ligands; Coordinated amide ligands; Dioxygen activation
Electrochemical study with cavity microelectrode containing clay-supported Mn(III)salen complex – Dioxygen activation with cytochrome P450 model
Keywords: فعال سازی دی اکسیژن; Schiff base complexes; Montmorillonite; Cavity microelectrode; Cyclic voltammetry; Dioxygen activation; Biomimetic oxidation catalyst
The reversible depletion and reconstitution of a copper ion in Coprinus cinereus laccase followed by spectroscopic techniques
Keywords: فعال سازی دی اکسیژن; Dioxygen activation; Laccase; Multicopper oxidase; Coprinus cinereus; Copper
Copper-mediated intramolecular oxidative N-dealkylation of a bis(ferrocenyl)pyridyl ligand
Keywords: فعال سازی دی اکسیژن; Bis(ferrocene)amides; Copper complexation; Dioxygen activation; N-dealkylation
Synthesis and characterization of a family of binuclear non-heme iron monooxygenase model compounds: Evidence for a “phenolate/amide carbonyl (PAC) shift” upon oxidation
Keywords: فعال سازی دی اکسیژن; Binuclear iron; Non-heme iron; Carboxylate shift; sMMO; Di-μ-alkoxy diferric; Dioxygen activation
The porphyrin complex catalyzed dioxygen activation in presence of solid inorganic phosphates and small quantities of t-BuOOH
Keywords: فعال سازی دی اکسیژن; Phosphates; Cyclohexene; Oxidation; Catalysis; Porphyrin; Dioxygen activation
Activation of dioxygen by an yttrium iodide adduct: First example of an yttrium superoxide displaying also a rare 1,1-bridging mode of the superoxide ligand
Keywords: فعال سازی دی اکسیژن; Superoxide; Yttrium; Structure; Iodide; Dioxygen activation
From activation of dioxygen to formation of high-valent oxo species: Ab initio DFT studies
Keywords: فعال سازی دی اکسیژن; Manganese porphyrin; Dioxygen activation; Homogeneous catalysis; Density functional calculations
Kinetic studies on the reaction between Trametes villosa laccase and dioxygen
Keywords: فعال سازی دی اکسیژن; Dioxygen activation; Laccase; Stopped-flow kinetics; Steady state kinetics; Multi-copper oxidase; Trametes villosa; Metallo-enzyme
Preparation of dehydro-l-ascorbic acid dimer by air oxidation of l-ascorbic acid in the presence of catalytic amounts of copper(II) acetate and pyridine
Keywords: فعال سازی دی اکسیژن; Ascorbic acid; Dehydroascorbic acid dimer; Copper(II) acetate/pyridine; Dioxygen activation;
Reactions of the diiron(IV) intermediate Q in soluble methane monooxygenase with fluoromethanes
Keywords: فعال سازی دی اکسیژن; Soluble methane monooxygenase; Hydroxylase; Fluorocarbon oxidation; Dioxygen activation; Enzyme kinetics;
Subzero-temperature stabilization and spectroscopic characterization of homogeneous oxyferrous complexes of the cytochrome P450 BM3 (CYP102) oxygenase domain and holoenzyme
Keywords: فعال سازی دی اکسیژن; Mono-oxygenase; Dioxygen activation; Oxyferrous heme iron; Magnetic circular dichroism; Cryoenzymology; Cysteinate-ligated heme iron; Cytochrome P450 BM3;
Basic approach to development of environment-friendly oxidation catalyst materials. Mononuclear hydroperoxo copper(II) complexes
Keywords: فعال سازی دی اکسیژن; Dioxygen activation; Mononuclear copper complexes; Hydroperoxide; Environment-friendly materials; Ligand design;