Keywords: اثر ایزوتوپ سینتیک; Amine dehydrogenase; Amine oxidase; Quinoprotein; Posttranslational modification; Redox cofactor; Tryptophan; AADH; aromatic amine dehydrogenase; CTQ; cysteine tryptophylquinone; KIE; kinetic isotope effect; QHNDH; quinohemoprotein amine dehydrogenase; LT
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Keywords: اثر ایزوتوپ سینتیک; Excited-state proton transfer; Photoacid; Time-resolved fluorescence; Nonradiative rate; Kinetic isotope effect;
Keywords: اثر ایزوتوپ سینتیک; Biomass; Sustainability; Catalysis; Multifunctional; Catalyst design; 1,2-PDO; 1,2-propanediol; 1,3-PDO; 1,3-propanediol; 2-MF; 2-methylfuran; ALD; atomic layer deposition; A&AEM; alkali & alkaline earth metals, ATR-FTIR, attenuated total reflectance-Four
Keywords: اثر ایزوتوپ سینتیک; Encapsulation; Gold nanoparticles; Heterogeneous catalysis; Silica; Formic acid; Hydrogen; ATR-FTIR; Kinetic isotope effect;
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Heart; Perfusion; Glucose metabolism; NMR; Deuterium;
Keywords: اثر ایزوتوپ سینتیک; Cellulose methanization; Competition for acetate; Fraction of methane produced from H2/CO2; Kinetic isotope effect; Sediments of tropical lakes; Syntrophic acetate oxidation;
Keywords: اثر ایزوتوپ سینتیک; Methane steam reforming; Microkinetic model; Kinetic isotope effect; Nickel; Rhodium;
Keywords: اثر ایزوتوپ سینتیک; Equilibrium isotope fractionation factor; The three-isotope method; Kinetic isotope effect; Isotope exchange kinetics;
Keywords: اثر ایزوتوپ سینتیک; Lipoxygenase; Kinetic isotope effect; Arachidonic acid
Keywords: اثر ایزوتوپ سینتیک; Ribonuclease; Transition state; Enzyme catalysis; Kinetic isotope effect
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Density functional theory; Propanoic acid; Dehydrogenation; Palladium
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Ribozyme; RNA catalysis; Labeled nucleotide; Transition state
Keywords: اثر ایزوتوپ سینتیک; Solvent isotope effect; Flavoprotein; Oxidase; Dehydrogenase; Enzyme kinetics; Kinetic isotope effect
Keywords: اثر ایزوتوپ سینتیک; Selenium; Reduction; Oxygen isotope ratios; Kinetic isotope effect; Dissimilatory selenium reduction; Sulfurospirillum barnesii SES-3;
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Equilibrium isotope effect; Inter-nuclear quantum effect; Biocatalysis; Centroid potential energy; Multi-scale molecular simulation
Keywords: اثر ایزوتوپ سینتیک; Chain reaction; Coenzyme Q; Kinetic isotope effect; Lipid peroxidation; Mitochondria respiration; Polyunsaturated fatty acid; Free radicals;
Keywords: اثر ایزوتوپ سینتیک; Electrooxidation; Electrocatalysis; Fuel cell; Kinetic isotope effect; Formic acid;
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Isotopic fractionation and enrichment factors; Marine diatom; Modified Monod kinetics; N-substrates; Ammonium inhibition
Keywords: اثر ایزوتوپ سینتیک; Alcohol; Selective oxidation; Gold; Chromium; Hydrotalcite; UV-Raman; Heterogeneous catalysis; Supported catalysts; Kinetic isotope effect
Keywords: اثر ایزوتوپ سینتیک; Isomerization; Allenamide; Allene; Reaction mechanism; DFT; Kinetic isotope effect;
New insights and tools for the elucidation of lipase catalyzed esterification reaction mechanism in n-hexane: The synthesis of ethyl butyrate
Keywords: اثر ایزوتوپ سینتیک; CALB; immobilized lipase-B from Candida antarcticaon acrylic resin - Novozyme 435; KIE; kinetic isotope effect; EIE; equilibrium isotope effect; AIC; Akaike's Information Criterion; df; degrees of freedom; Ethyl butyrate; Lipase-catalyzed esterificati
15(V/K) kinetic isotope effect and steady-state kinetic analysis for the transglutaminase 2 catalyzed deamidation and transamidation reactions
Keywords: اثر ایزوتوپ سینتیک; Isotope effects; Polyamidation; Deamidation; Transglutaminase; Steady-state kinetics; KIE; kinetic isotope effect; TG2; transglutaminase 2, tissue transglutaminase; Z-Gln-Gly; N-Benzyloxycarbonyl-l-Glutaminylglycine;
Tunnelling and the kinetic isotope effect in CH3+CH4âCH4+CH3: An application of semiclassical transition state theory
Keywords: اثر ایزوتوپ سینتیک; Semiclassical transition state theory; Kinetic isotope effect; Hindered rotor; Hydrogen exchange;
DFT investigation on the metabolic mechanisms of theophylline by cytochrome P450 monooxygenase
Keywords: اثر ایزوتوپ سینتیک; Theophylline; Cytochrome P450 monooxygenase; N-demethylation; Density functional theory; Kinetic isotope effect;
Dynamic isotope equations for 13CH4 and 13CO2 describing methane formation with a focus on the effect of anaerobic respiration in sediments of some tropical lakes
Keywords: اثر ایزوتوپ سینتیک; Anaerobic respiration; Kinetic isotope effect; Sediment methanization; Syntrophic acetate oxidation; Summary total and heavier carbon balances; Tropical lakes;
Trichloroethene (TCE) hydrodechlorination by NiFe nanoparticles: Influence of aqueous anions on catalytic pathways
Keywords: اثر ایزوتوپ سینتیک; Trichloroethene; Hydrodechlorination; NiFe; Bimetallic nanoparticle; Kinetic isotope effect; Aqueous deactivation;
Effects of elevated CO2 on shell 13C and 18O content and growth rates in the clam Scapharca broughtonii
Keywords: اثر ایزوتوپ سینتیک; Ocean acidification; Stable isotopes; Bivalve; Kinetic isotope effect; Calcification;
Kinetic isotope effect in the oxygen reduction reaction (ORR) over Fe-N/C catalysts under acidic and alkaline conditions
Keywords: اثر ایزوتوپ سینتیک; Oxygen reduction reaction; Non-precious metal catalysts; Kinetic isotope effect;
Secondary kinetic deuterium isotope effects. The CC cleavage of labeled tetramethylethylenediamine radical cations-Who gets to keep the electron?
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Deuterium labeling; Simple cleavage; Hyperconjugation;
Insights into the role of methionine synthase in the universal 13C depletion in O- and N-methyl groups of natural products
Keywords: اثر ایزوتوپ سینتیک; l-methionine; l-methionine synthase (EC 2.1.1.14); O-methyl and N-methyl groups; 13C/12C isotope fractionation; 13C NMR; QM/MM theoretical calculation; AdoMet; S-adenosylmethionine; EA; elemental analyzer; EIE; equilibrium isotope effect; Hcy; homocystein
Catalytic C-H oxidations by nonheme mononuclear Fe(II) complexes of two pentadentate ligands: Evidence for an Fe(IV) oxo intermediate
Keywords: اثر ایزوتوپ سینتیک; Nonheme; Iron; Oxidation catalysis; Kinetic isotope effect; H-atom abstraction;
Ultrafast excited state intermolecular proton transfer dynamics of 2-(4â²-Pyridyl)benzimidazole inside the nanocavity of reverse micelles
Keywords: اثر ایزوتوپ سینتیک; Excited state intermolecular proton transfer; AOT reverse micelle; Kinetic isotope effect; Fluorescence; Time resolved spectroscopy;
Mechanistic study for the selective oxidation of benzene and toluene catalyzed by Fe(ClO4)2 in an H2O2-H2O-CH3CN system
Keywords: اثر ایزوتوپ سینتیک; Iron(II) perchlorate; Oxidation; Hydrogen peroxide; Ring hydroxylation; Chain hydroxylation; Selectivity; Kinetic isotope effect;
Chloro benzoate cyanine picolinium photoacid excited-state proton transfer to water
Keywords: اثر ایزوتوپ سینتیک; Excited-state proton transfer; Photoacid; Time-resolved fluorescence; Nonradiative rate; Kinetic isotope effect;
The protonation state around TyrD/TyrD⢠in photosystem II is reflected in its biphasic oxidation kinetics
Keywords: اثر ایزوتوپ سینتیک; Chl; chlorophyll; DAD; 2,3,5,6-tetramethyl-p-phenylenediamine; CW EPR; continuous wave electron paramagnetic resonance; DMSO; dimethyl sulfoxide; H/D; hydrogen-deuterium exchange; HEPES; 4-(2-hydroxyethyl)-1-piperazineethanesulfonic acid; KIE; kinetic iso
Evidence for proton tunneling and a transient covalent flavin-substrate adduct in choline oxidase S101A
Keywords: اثر ایزوتوپ سینتیک; CHO; choline oxidase; DAD; donor-acceptor distance; D-choline; 1,2-[2H4]-choline; FAD; flavin adenine dinucleotide; KIE; kinetic isotope effect; QM; quantum mechanical; TRS; tunneling-ready-state; TST; transition state theory; Choline oxidase; Flavin-subs
Novel visible-light-driven Z-scheme Bi12GeO20/g-C3N4 photocatalyst: Oxygen-induced pathway of organic pollutants degradation and proton assisted electron transfer mechanism of Cr(VI) reduction
Keywords: اثر ایزوتوپ سینتیک; Z-scheme; Bi12GeO20/g-C3N4 composite; Oxygen-induced pathway; Kinetic isotope effect; Proton assisted electron transfer;
Hydrogen atom mobility, kinetic isotope effects and tunneling on interstellar ices (Ih and ASW)
Keywords: اثر ایزوتوپ سینتیک; Astrochemistry; Hydrogen; Deuterium; Surface diffusion; Kinetic isotope effect; Rate constant; Tunneling; Barrier height; Transition state theory; Icy grain; Crystalline ice; Amorphous solid water; Binding energies;
Clumped isotope effects during OH and Cl oxidation of methane
Keywords: اثر ایزوتوپ سینتیک; Clumped isotopes; Kinetic isotope effect; Methane;
Oxygen isotope fractionation in the CaCO3-DIC-H2O system
Keywords: اثر ایزوتوپ سینتیک; Oxygen isotopes; δ18O; Calcite; CaCO3; Kinetic isotope effect; Vital effect; Foraminifera; Coral;
Sources of variability in fatty acid (FA) biomarkers in the application of compound-specific stable isotopes (CSSIs) to soil and sediment fingerprinting and tracing: A review
Keywords: اثر ایزوتوپ سینتیک; CSIA; Compound-specific stable isotope analysis; Tracking; Erosion; Water quality; Land use; PSE; pressurized solvent extraction; BMP; beneficial or best management practice; CAM; Crassulacean acid metabolism; CSSI; compound-specific stable isotope; CV; c
Photo-induced formation of cyclopropanols from α-ketoamides via γ-CH bond activation
Keywords: اثر ایزوتوپ سینتیک; Photo chemical reaction; Cyclopropanols; Kinetic isotope effect; α-Ketoamides; Ring-opening reactions;
Effect of Zn2 + binding and enzyme active site on the transition state for RNA 2′-O-transphosphorylation interpreted through kinetic isotope effects
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Transition state; Transphosphorylation; Zn2 + binding; Enzyme
Secondary kinetic deuterium isotope effect in oxidative addition reaction of cycloplatinated(II) complexes with MeI
Keywords: اثر ایزوتوپ سینتیک; Kinetic isotope effect; Platinum; Kinetic and mechanism; Oxidative addition
Microkinetic evaluation of normal and inverse kinetic isotope effects during methane steam reforming to synthesis gas over a Ni/NiAl2O4 model catalyst
Keywords: اثر ایزوتوپ سینتیک; Microkinetic modelling; Methane steam reforming; Kinetic isotope effect; Reaction pathway; Partial equilibrium
Dynamics of the active site architecture in plant-type ferredoxin-NADP+ reductases catalytic complexes
Keywords: اثر ایزوتوپ سینتیک; FNR; ferredoxin-NADP+ reductase; FPR; bacterial-type FNR; AnFNR; FNR from the cyanobacterium Anabaena PCC 7119; PsFNR; FNR from Pisum sativum; XaFPR; FPR from Xanthomonas axonopodis pv. citri; EcFPR; FPR from Escherichia coli; FNRox; FNR in the fully oxid
Kinetic and mechanistic study of dry (CO2) reforming of methane over Rh-substituted La2Zr2O7 pyrochlores
Keywords: اثر ایزوتوپ سینتیک; Dry reforming; La-oxycarbonates; Pyrochlores; Lattice oxygen; Kinetic isotope effect; Transient pulsing
Theoretical investigations on the reaction kinetics of CH3OCl/CD3OCl with chloride ion
Keywords: اثر ایزوتوپ سینتیک; Reaction mechanism; Direct dynamics; Rate constant; Kinetic isotope effect;
Water in Photosystem II: Structural, functional and mechanistic considerations
Keywords: اثر ایزوتوپ سینتیک; AQP; aquaporin; bR; bacteriorhodopsin; BRC; bacterial reaction center; CYP; cytochrome P450; FTIR; Fourier transform infrared; KIE; kinetic isotope effect; LCS; large channel system; MD; molecular dynamics; MSMD; multiple steered molecular dynamics; P680;
H-D kinetic isotope effects of alcohol electrooxidation on Au, Pd and Pt electrodes in alkaline solutions
Keywords: اثر ایزوتوپ سینتیک; Alcohol electrooxidation; Kinetic isotope effect; Rate-determining step; Precious metals;