کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
6454044 | 1418813 | 2017 | 10 صفحه PDF | دانلود رایگان |
- Novel Z-scheme visible-light-driven Bi12GeO20/g-C3N4 photocatalysts were prepared.
- The Bi12GeO20/g-C3N4 composites exhibited enhanced photocatalytic activities.
- The degradation of microcystin-LR and RhB is an oxygen-induced reaction.
- The reduction of aqueous Cr(VI) is a proton assisted electron transfer reaction.
We successfully synthesized novel solid state Z-scheme visible-light-driven Bi12GeO20/g-C3N4 composite photocatalysts and investigated their photocatalytic activities for degradation of microcystin-LR and RhB, and for reduction of aqueous Cr(VI). The TEM and HRTEM images clearly showed the heterogeneous nanostructures at the interface between Bi12GeO20 and g-C3N4. The as-prepared Bi12GeO20/g-C3N4 composites exhibited enhanced photocatalytic activities for the degradation of microcystin-LR and RhB aqueous solution and reduction of aqueous Cr(VI) as compared to the pure Bi12GeO20 and g-C3N4 under visible-light irradiation. On the basis of the radical species trapping experiments and ESR analyses, O2â and h+ were confirmed to be the mainly active species involved in the degradation of organic pollutants and this reaction was identified to be an oxygen-induced pathway. Meanwhile, combined with the in situ ATR-FTIR spectroscopy and kinetic isotope effect investigations, the photocatalytic reduction of aqueous Cr(VI) was identified as a proton assisted electron transfer reaction. Moreover, the enhanced photocatalytic activities of the Bi12GeO20/g-C3N4 composites can be attributed to the improved photo-absorption properties and effective separation of photo-induced charge carriers caused by the Z-scheme system of the as-prepared Bi12GeO20/g-C3N4 composites.
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Journal: Applied Catalysis B: Environmental - Volume 207, 15 June 2017, Pages 17-26