Keywords: dbiy; 1,3-di-t-butylimidazol-2-ylidene; dpp; 2,9-diphenyl-1,10-phenanthroline; dppe; 1,2-bis(diphenylphosphino)ethane; MLCT; metal-to-ligand charge transfer; NHC; N-heterocyclic carbene; PPh3; triphenylphosphine; P(OPh)3; triphenylphosphite; P(O-o-cresyl)
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Keywords: bpy; 2,2â²-bipyridine; dppcb; cis,trans,cis-1,2,3,4-tetrakis-(diphenylphosphanyl)cyclobutane; dppen; cis-1,2-bis-(diphenylphosphanyl)ethene; MLCT; metal to ligand charge transfer; NMR; Nuclear Magnetic Resonance; UV/vis; ultraviolet/visible light; Solar
Keywords: bpy; 2,2â²-bipyridine; Im; imidazole; MLCT; metal-to-ligand charge transfer; NAD; nicotinamide adenine dinucleotide; NAP; naphthyridine; NHC; N-heterocyclic carbene; phen; 1,10-phenanthroline; pic; 4-picoline; PPh3; triphenylphosphine; py; pyridine; TN;
Keywords: MOFs; metalorganic frameworks; PL; photoluminescence; PCPs; porous coordination polymers; LMCT; ligand-to-metal charge transfer; MLCT; metal-to-ligand charge transfer; LUMO; lowest unoccupied molecular orbital; CB; conduction band; SBUs; secondary buildin
Keywords: 4,4â²-bpy; 4,4â²-bipyridyl; A; adenine; AMP; 5â²- adenosine monophosphate; BAP; bis(arginyl)porphyrin; bpy; 2,2â²-bipyridyl; C; cytosine; cpdppz(CH2)nNH2; N-(12-cyano-12,13-dihydro-11H-cyclopenta[b]dipyrido[3,2-h:2â²,3â²-j]- phenazine-12-carbonyl)-1
Keywords: A; electron acceptor; acac; acetylacetonate; Alq3; tris(8-hydroxyquinolinato)aluminum; BAlq; bis(2-methyl-8-quinolinolato)-mono(4-phenylphenolato)aluminum; BCP; 2,9-dimethyl-4,7-diphenyl-1,10-phenanthroline; Bepp2; bis[2(2â²-hydroxyphenyl)pyridine]beryll
Keywords: AC; alternating current or asymptotically correct; ADF; Amsterdam density functional; AM1; Austin model 1 semi-empirical method; au; atomic units; BBO; β-barium borate; CC; coupled-cluster; CHF; coupled Hartree-Fock; CI; configuration interaction; CNDO
Keywords: LE; low-energy; 3CC; triplet cluster-centered; XMCT; halide-to-metal charge transfer; XLCT; halogen-to-ligand charge transfer; MLCT; metal-to-ligand charge transfer; HE; high-energy; DFT; density functional theory; SCO; spin crossover; bib; 1,4-bis(1-imid
Keywords: 1,4-biyb; 1,4-bis(imidazol-1-ylmethyl)benzene; 2,6-ndc; 2,6-naphthalenedicarboxylate; 2-cmsnH2; 2-carboxymethylsulfanyl nicotinic acid; 3-dpye; N,Nâ²-bis(3-pyridinecarboxamide)-1,2-ethane; 4,4â²-bpy; 4,4â²-bipyridine; 4,4â²-obb; 4,4â²-oxybis(benzoate
Keywords: Alq3; tris(8-hydroxyquinolinato) aluminum(III); BCP; bathocuproine; BHJSCs; bulk heterojunction solar cells; BAlq-13; bis(2-methyl-quinolin-8-olato)(2,6-diphenylphenolato)aluminum(III); Bphen; bathophenanthroline; bpy; 2,2â²-bipyridine; bq; 2,2â²-biquin
Keywords: ICT; intramolecular charge transfer; MLCT; metal-to-ligand charge transfer; LMCT; ligand-to-metal charge transfer; BODIPY; 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; ATP; adenosine tri phosphate; SEM; scanning electron microscopy; DPA; di-(2-picolylamine
Keywords: Aβ; amyloid-β peptide; AD; Alzheimer's disease; ASBA; 2-amino-5-sulfobenzoic acid; BDC; 1-4-benzendicarboxylate; BHC; mellitic acid; BIMB; 1,4-bis(1H-imidazol-1-yl)butane; 2,2Ë-Bipy; 2,2â²-Bipyridine; 4,4Ë-Bipy; 4,4â²-Bipyridine; BPTC; 3,3â²,5,
Keywords: Ln; lanthanides; NIR; near-infrared; MOF; metal-organic framework; SSL; solid-state lighting; PL; photoluminescence; LED; light emitting diode; WLED; white-light emitting diode; OLED; organic light emitting diode; CIE; commission Internationale d'Eclair
The chameleon-like coordinating ability of 2,3-di(pyridyl)pyrazine-type ligands
Keywords: BL; bridging ligand; DCM; dichloromethane; DFT; density functional theory; DMF; N,N-dimethylformamide; fsTA; femtosecond transient absorption spectra; LLCT; ligand-to-ligand charge-transfer; MeCN; acetonitrile; Meim; 1-methylimidazole; MLCT; metal-to-liga
Keywords: PL; photoluminescent; AgNPs; silver nanoparticle; NPs; nanoparticles; AN&N; analytical nanoscience and nanotechnology; TEMPO; 2,2,6,6-tetramethylpiperidine-1-oxyl free radical; NC; nanocellulose; c-NC; carboxylated nanocellulose; bpy; 2,2â²-bipyridine; 4
Keywords: AA; amino acid residue; ADPA; anthracene-9,10-dipropionic acid disodium salt; BSA; bovine serum albumin; 1O2; singlet molecular oxygen; DAS; decay associated spectra; DOPA; dihydroxyphenylalanine; HSA; human serum albumin; MLCT; metal-to-ligand charge-tra
Keywords: phen, 1,10-phenanthroline; Me3NO, trimethylamine N-oxide; AgOTf, silver trifluoromethanesulfonate; LC, ligand-centered; IL, intraligand; MLCT, metal-to-ligand charge transfer; THF, tetrahydrofuranRhenium; Diisocyanide; Homodinuclear; MLCT; Luminescence
Keywords: Optical materials; Thin films; Vacuum deposition; Electrochemical properties; DFT; density functional theory; LEC; light-emitting electrochemical cell; CIE; Commission Internationale de L'Eclairage; OLED; organic light-emitting diode; iTMC; ionic transiti
Keywords: Ruthenium; Terpyridyl complexes; Intraligand; Transient absorption; Diethylenetriamine; Excited state lifetime; MLCT; ILCT
Keywords: Ruthenium photosensitiser; MLCT; Pourbaix diagram; Ru-aquo species; DFT;
Novel chemical sensor for detection Ca(II) ions based on ferutinin
Keywords: Medicinal probe; Ca(II); MLCT; Absorption ratiometric; Fluorescence enhancement;
Photophysics of a mono-nuclear tetrahedral silver(I)N4 core and its copper(I) analog
Keywords: X-ray structure; Cyclic voltammetry; Emission; MLCT; DFT;
Photoactivated [Mn(CO)3Br(μ-bpcpd)]2 induces apoptosis in cancer cells via intrinsic pathway
Keywords: CORM; Carbon monoxide releasing molecule; CO/aCORM; Photoactivated MnCORM; RPMI; Rosewell Park Memorial Institute; PI; Propidium iodide; DMEM; Dulbecco's Modified Eagle Medium; MTT; (3-(4,5-Dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide); OD; Optic
Metal complex strategies for photo-uncaging the small molecule bioregulators nitric oxide and carbon monoxide
Keywords: bpy; 2,2â²-bipyridine; CORM; carbon monoxide releasing moiety; CrONO; trans-CrIII(cyclam)(ONO)2+; CW; continuous wave; cyclam; 1,4,8,11 tetraazacyclotetradecane; DAF-FM DA; 4-amino-5-methylamino-2â²,7â²-difluorofluorescein diacetate; DFT; density funct
Labelling proteins and peptides with phosphorescent d6 transition metal complexes
Keywords: Aβ; amyloid-β; BRD4; bromodomain-containing protein 4; BSA; bovine serum albumin; COX-2; cyclooxygenase-2; D/P; dye:protein ratio, used to quantify the number of metal complexes attached per protein; DNA; deoxyribonucleic acid; EC50; half maximal effect
Heteroleptic diimine-diphosphine Cu(I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and perspective applications
Keywords: ACN; acetonitrile; ATRA; atom transfer radical addition; bpy; 2,2â²-bipyridine; CDC; cross-dehydrogenative coupling; DCM; dichloromethane; DFT; density functional theory; DHA; dihedral angle; DMF; dimethylformamide; DSSC; dye sensitized solar cell; FC; F
Luminescent cyclometalated-pentafluorophenyl PtII, PtIV and heteropolynuclear complexes
Keywords: Br-Hpbt; 2-(4-bromophenyl)benzothiazole; CC; cluster-centered; cyclen; 1,4,7,10-tetraazacyclododecane; Hbzq; 7,8-benzo[h]quinoline; Hdfppy; 2-(2,4-difluorophenyl)pyridine; HE; high energy; HOMO; highest occupied molecular orbital; Hpbt; 2-phenylbenzothiaz
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Keywords: 6Mesbpy; 6,6â²-mesityl-2,2â²-bipyridine; BIH; 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole; BNAH; 1-benzyl-1,4-dihydronicotinamide; bpy; 2,2-bipyridine; CV; cyclic voltammetry; dmb; 4,4â²-dimethyl-2,2â²-bipyridine; D; electron donor; DMA; N,
Structural difference of palm based Medium- and Long-Chain Triacylglycerol (MLCT) further reduces body fat accumulation in DIO C57BL/6J mice when consumed in low fat diet for a mid-term period
Keywords: Interesterification; Structured lipid; Medium chain fatty acid; Obesity; MLCT;
Sustainable metal complexes for organic light-emitting diodes (OLEDs)
Keywords: 3MLCT; triplet metal-ligand charge transfer; 4MTPD; N,Nâ²-diphenyl-N,Nâ²-(3-methyl)-1,1â²-biphenyl-4,4â²-diamine; acac; acetylacetonate; AIEE; aggregation induced enhanced emission; An; (ortho)-anisyl; BAlq; bis(2-methyl-8-quninolinato)-4-phenylphen
Recent theoretical progress in the organic/metal-organic sensitizers as the free dyes, dye/TiO2 and dye/electrolyte systems; Structural modifications and solvent effects on their performance
Keywords: DSSC; dye-sensitized solar cells; LUMO; lowest unoccupied molecular orbital; HOMO; highest occupied molecular orbital; FF; fill factor; VOC; open circuit voltage; JSC; short-circuit photocurrent density; ÎGinj; free energy change of electron injection; Î
Probing the use of long lived intra-ligand Ï-Ï* excited states for photocatalytic systems: A study of the photophysics and photochemistry of [ReCl(CO)3(dppz-(CH3)2)]
Keywords: MLCT; metal-to-ligand charge transfer; FTIR; Fourier transform infrared; TRIR; time-resolved infrared; IL; intra-ligand; LUMO; lowest unoccupied molecular orbital; DNA; deoxyribonucleic acid; bpy; 2,2â²-bipyridine; dppz; dipyrido[3,2-a:2â²,3â²-c]phenaz
Photo-physical studies of ruthenium(II) tris(1,10-phenanthroline) confined within a polyhedral zinc(II)-trimesic acid metal organic framework
Keywords: RuPhen; Ru(II) tris(1,10-phenanthroline); RuBpy; Ru(II) tris(2,2â²-bipyridine); MLCT; metal-to-ligand charge transfer state; LF; ligand field state; MOF; metal organic framework; Ru(II)polypyridyl complexes; Fluorescence; Metal organic framework; Photo-c
Dinuclear fused salen complexes of group-10 metals: Peculiarity of the crystal structure and near-infrared luminescence of a bis(Pt-salen) complex
Keywords: MLCT; metal-to-ligand charge transfer; MMLCT; metalmetal-to-ligand charge transfer; DCB; o-dichlorobenzene; Na-TFPB; sodium tetrakis(3,5-bis(trifluoromethyl)phenyl)borate; Metal-metal contact; Ï-Conjugated system; Photoluminescence; Near-infrared emissio
Synthesis, characterization and molecular modeling of new ruthenium(II) complexes with nitrogen and nitrogen/oxygen donor ligands
Keywords: Hzpy; 2-hydrazinopyridine hydrochloride; DABA; 3,4-diaminobenzoic acid; Bipy; 2,2â²-bipyridine; DSSC; dye sensitized solar cell; MLCT; metal-ligand charge transfer; Ruthenium(II); Spectroscopy; Thermal stability; Molecular modeling;
Photophysical properties of [Ru(2,2â²-bipyridine)3]2+ encapsulated within the Uio-66 zirconium based metal organic framework
Keywords: RuBpy; [Ru(II)(2,2â²-bipyridine)3]2+; MOF; Metal Organic Framework; MLCT; metal-to-ligand charge transfer; BDC; Benzene 1,4-Dicarboxylate; DMF; N,N Dimethyl Formamide; DEA; Diethylamine; FWHM; Full Width at Half Maximum; Ruthenium; Metal organic framewor
Photoredox reactions of binuclear iron(II) and (III) disulfide complexes. Disulfide as CT acceptor and donor
Keywords: Iron complexes; Disulfide complexes; Photoredox reactions; MLCT; LMCT;
Small differences in structure, a large difference in activity - Comparing a new Ru(II)-3-hydroxyiminoflavanone complex with analogous Ru(II) compounds
Keywords: 1; 3-hydroxyiminoflavanone; 2; cis-dichlorido(3-nitrosoflavone)(3-hydroxyiminoflavanone)-ruthenium(II); 3; cis-dichloridobis(3-imino-2-methoxyflavanone)ruthenium(II); 4; cis-dichloridobis(3-imino-2-ethoxyflavanone)ruthenium(II); APTT; activated partial th
Recent developments on optical and electrochemical sensing of copper(II) ion based on transition metal complexes
Keywords: AAS; atomic absorption spectroscopy; AIPE; aggregation-induced phosphorescent emission; bpy; 2,2â²-bipyridine; CT; charge transfer; DFT; density functional theory; DPA; dipicolylamine; EDTA; ethylenediaminetetraacetic acid; EPA; U.S. Environmental Protec
Ferrocene chromophores continue to inspire. Fine-tuning and switching of the second-order nonlinear optical response
Keywords: A; acceptor; Az+; azulenylium; BINOL; 1,1â²-bi-2-naphthol; BLA; bond length alternation; BODIPY; 4,4-difluoro-4-bora-3a,4a-diaza-s-indacene; CNS; cyanostilbene; Cp; cyclopentadiene; CPCM; Cossi and Barone's conductor like polarisable continuum model; C
Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis
Keywords: δ; Chemical shift; 1D; One dimension; 2D; Two dimensions; Ac; Acetate; Acac; Acetylacetonate; Ad; Adamantyl; Ar; Aryl; BARF; Tetrakis(3,5-di-trifluoromethylphenyl)borate); Bipy; 2,2â²-bipyridine; Bu; Butyl; Bn; Benzyl; COD; Cyclooctadiene; COE; Cyclooct
Evolution of 2, 3â²-bipyridine class of cyclometalating ligands as efficient phosphorescent iridium(III) emitters for applications in organic light emitting diodes
Keywords: MLCT; metal-to-ligand charge transfer; LC; ligand centered; MC; metal centered; ILET; intramolecular inter-ligand energy transfer; SOC; spinâorbit coupling; ξIr; spinâorbit coupling constant; ISC; intersystem crossing; LEECs; light emitting electro
So-called “dual emission” for 3MLCT luminescence in ruthenium complex ions: What is really happening?
Keywords: Ruthenium; MLCT; Phosphorescence; Dual emission; Ion pairs
The versatile ruthenium(II/III) tetraazamacrocycle complexes and their nitrosyl derivatives
Keywords: acn; acetonitrile; 4-acpy; pyridine-4-acetyl; acv; (acyclovir), 2-amino-1,9-dihydro-9-[(2-hydroxyethoxy)methyl]-6H-purin-6-one); am(m)ine; ammine, amine, and/or tetraazamacrocycle; ampy; 2-aminomethylpyridine; [15]aneN4; 1,4,8,12-tetraazacyclopentadecane;
Ru(II) complexes bearing guanidinium ligands as potent anticancer agents
Keywords: PBS; phosphate buffered saline; ROS; reactive oxygen species; MTT; 3-(4,5-dimethylthiazol-2-yl)-2,5-diphenyltetrazolium bromide; ESI-MS; electrospray ionization mass spectrometry; FBS; fetal bovine serum; PI; propidium iodide; RIPA; radio-immunoprecipitat
Synthesis, characterization, spectroscopic and electrochemical studies of donor-acceptor ruthenium(II) polypyridine ligand derivatives with potential NLO applications
Keywords: Ruthenium complexes; Solvatochromic effect; MLCT; NLO; Donor-Acceptor effect;
MLCT based colorimetric probe for iron having D–A–D type architecture of benzo[2,1,3]thiadiazole acceptor and thiophene donor with azomethine pendant arm
Keywords: Donor–acceptor; Intramolecular charge transfer; MLCT; Iron sensor; Azomethine
Synthesis of trinuclear Pd–Ru–Pd porphyrin complexes with axially ligated Pd centers. Prominent metal-to-ligand charge transfer band in the visible region
Keywords: MLCT; Ru–porphyrin; Trinuclear complex
On the viability of ruthenium (II) N-heterocyclic carbene complexes as dye-sensitized solar cell (DSSCs): A theoretical study
Keywords: Ruthenium complex; N-heterocyclic carbene; TDDFT; MLCT; NTO;
DNA interaction, cytotoxicity, apoptotic activity, cell cycle arrest, reactive oxygen species and mitochondrial membrane potential assay induced by ruthenium(II) polypyridyl complexes
Keywords: Ruthenium(II) complexes; Cytotoxicity in vitro; Apoptosis; Cell cycle arrest; Mitochondrial membrane potential; DNA-binding; NHPIP; 2-(3-nitro-4-hydroxylphenyl)imidazo[4,5-f][1,10]phenanthroline; AHPIP; 2-(3-amino-4-hydroxylphenyl)imidazo[4,5-f][1,10]phen