
Redox cycling in the activation of peroxides by iron porphyrin and manganese complexes. ‘Catching’ catalytic active intermediates
Keywords: t-BuOOH, tert-butyl hydroperoxide; CumOOH, cumyl hydroperoxide; MPPH, 2-methyl-1-phenylpropan-2-yl hydroperoxide; TDFPPS, meso-tetrakis(2,6-difluoro-3-sulfonatophenyl)porphyrin; TDCPPS, meso-tetrakis(2,6-dichloro-3-sulfonatophenyl)porphyrin; TMPyP, meso-t