Keywords: Ac; acetyl; AD-mix; asymmetric dihydroxylation mix; ATP; adenosine triphosphate; Bn; benzyl; Boc; tert-butyloxycarbonyl; Bu; butyl (n-Bu, n-butyl; I; isobutyl; sec-Bu; sec-butyl; t-Bu; tert-butyl); Bz; benzoyl; CAL-B; Candida antartcia lipase-B; CAN; ceri
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Synthesis and hybridization properties of oligonucleotide analogues with novel acyclic triazole internucleotide linkages
Keywords: TBDPS; t-butyldimethylsilyl; DMT 4; 4â²-dimethoxytrityl; Nucleosides; DNA; Click chemistry; CuAAC; Thermodynamics;
Keywords: Nitro compounds; Natural products; Pharmaceuticals; Stereoselective synthesis; Organocatalysis; Metal catalysis; Nitronates; Nitrile oxides; AIBN; azobisisobutyronitrile; AZADO; 2-azaadamantane-N-oxyl; 9-BBN; 9-borabicyclo[3.3.1]nonane; BINAP; 2,2â²-bis(
Keywords: Ac; acetyl; acac; acetylacetonate; 9-BBN; 9-borabicyclo[3.3.1]nonane; Bn; benzyl; Boc; tert-butyloxycarbonyl; BOM; benzyloxymethyl; brsm; based on recovered starting material; Bz; benzoyl; CAN; ammonium cerium(IV) nitrate; Cbz; benzyloxycarbonyl; CD; circ
A silyl andrographolide analogue suppresses Wnt/β-catenin signaling pathway in colon cancer
Keywords: CRC; colorectal cancer; TBDPS; tert-butyldiphenylsilyl; GSK-3β; glycogen synthase kinase-3β; TCF/LEF; T-cell factor and lymphoid enhancer factor; PARP-1; poly (ADP-ribose) polymerase-1; Andrographolide analogue; Anti-cancer; Colorectal cancer; Wnt/β-ca
Exploring the influence of indololactone structure on selectivity for binding to the C1 domains of PKCα, PKCε, and RasGRP
Keywords: BCl3; boron trichloride; CAN; ceric ammonium nitrate; DAG; diacylglycerol; DBU; 1,8-diazabicyclo[5.4.0]undec-7-ene; DMAP; 4-dimethylaminopyridine; GEFs; guanine nucleotide exchange factors; LiHMDS; lithium hexamethyldisilazide; MRCKs; myotonic dystrophy k
Applications of Danishefsky's dienes in asymmetric Oxo-Diels-Alder reactions
Keywords: CAB; a stable chiral (acy1oxy)borane; TBME; tert-butyl methyl ether; EDOT; 3,4-ethylenedioxythiophene; CAN; a chiral Ce(IV) complex from ammonium cerium(IV) nitrate; TADDOL; α,α,αâ²,αâ²-tetraaryl-1,3-dioxolane-4,5-dimethanols; 5-C1-BIPOL; 5,5â²-dic
Stereoselective synthesis of 3-hydroxy-3-methylglutaryl-coenzyme A reductase inhibitors
Keywords: HMG-CoA reductase inhibitors; Statins; Chiral β-hydroxy-δ-lactone; Chiral 3,5-syn-diol acid; Asymmetric synthesis; Ac; acetyl; Ar; aryl; Bn; benzyl; Bz; benzoyl; n-Bu; butyl; t-Bu; tert-butyl; CDI; 1,1â²-carbonyldiimidazole; BINOL; 1,1â²-bi-2-naphthol
Design, synthesis, and structure-activity relationships of a series of novel N-aryl-2-phenylcyclopropanecarboxamide that are potent and orally active orexin receptor antagonists
Keywords: OX1R; orexin 1 receptor; OX2R; orexin 2 receptor; THF; tetrahydrofuran; TBDPS; tert-butyldiphenylsilyl; DMF; N,N-dimethylformamide; DIAD; diisopropyl azodicarboxylate; TBAF; tetra-n-butylammonium fluoride; DMSO; dimethyl sulfoxide; TEA; triethylamine; DCM
Intramolecular Diels-Alder reaction as a key step in tandem or sequential processes: a versatile tool for the synthesis of fused and bridged bicyclic or polycyclic compounds
Keywords: Diels-Alder; Natural product; One-pot; Sequential; Tandem; IMDA; intramolecular Diels-Alder; IMHDA; intramolecular hetero Diels-Alder; DA; Diels-Alder; IEDDA; intramolecular inverse-electron-demand Diels-Alder; DAIB or DIB; diacetoxyiodobenzene;
Recent developments in dynamic kinetic resolution
Keywords: Ac; acetyl; AIBN; 2,2â²-azobisisobutyronitrile; Ar; aryl; Atm; atmosphere; BARF; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; BINAP; 2,2â²-bis(diphenylphosphanyl)-1,1â²-binaphthyl; BINOL; 1,1â²-bi-2-naphthol; BIPHEP; 2,2â²-bis(diphenylphosphino)-1
Radicals in organic synthesis. Part 1
Keywords: (S,S)-BDPP; (2S,4S)-2,4-bis(diphenylphosphino)pentane; ABCVA; 4,4â²-azobis(4-cyanovaleric acid); ACCN; 1,1â²-azobis(cyclohexanecarbonitrile); AIBN; azobisisobutyronitrile; AMBN; azobismethylisobutyronitrile or 2-(1-cyano-1-methyl-propylazo)-2-methyl-but
Advances in the Baylis-Hillman reaction-assisted synthesis of cyclic frameworks
Keywords: Baylis-Hillman reaction; Cyclic compounds; Heterocycles; Nucleophilic substitution; Ac; acetyl; AIBN; 2,20-azobisisobutyronitrile; Aq; aqueous; Ar; aryl; 9BBN; 9-borabicyclo[3.3.1]nonane; BINAP; 2,20-bis(diphenylphosphanyl)-1,10-binaphthyl; BF3·Et2O; b
Application of hydrolytic kinetic resolution (HKR) in the synthesis of bioactive compounds
Keywords: Hydrolytic kinetic resolution; Terminal epoxides; Bis-epoxides; meso-Epoxides; Natural products; Synthesis; Biological activity; Ac; acetyl; AD; asymmetric dihydroxylation; AE; asymmetric epoxidation; Bn; benzyl; NBS; N-bromosuccinimide; Boc; t-butoxycarb
Asymmetric organocatalysis
Keywords: Ac; acetyl; Ar; aryl; BINOL; 1,1â²-bi-2-naphthol; Bn; benzyl; Boc; tert-butoxycarbonyl; Bu; butyl; Bz; benzoyl; Cbz; benzyloxycarbonyl; CPME; cyclopentyl methyl ether; Cy; cyclohexyl; DABCO; 1,4-diazabicyclo[2.2.2]octane; DBAB; dibenzylazodicarboxylate;
Enantioselective synthesis of steroids
Keywords: Steroids; Asymmetric inductions; Pool chiral; Enantioselectivity; Resolution; acac; acetylacetonate; 9-BBN; 9-bora-bicyclo[3.3.1]nonane; BHT; 2,6-di-tert-butyl-4-methylphenol; BINAP; 2,2â²-bis(diphenylphosphino)-1,1â²-binaphthyl; Binol; 1,1â²-binaphtha
Recent developments in the synthesis of oxepines
Keywords: CAN; ceric ammonium nitrate; Cy; cyclohexyl; dba; dibenzylideneacetone; DBU; 1,8-diazabicyclo[5.4.0]undec-7-ene; DEAD; diethyl azodicarboxylate; DMAP; N,N-4-dimethylaminopyridine; DMDO; dimethyldioxirane; Eu(fod)3; europium 6,6,7,7,8,8,8-heptafluoro-2,2-d
Evolution of the stereoselective pinacol coupling reaction
Keywords: Pinacol coupling; Reductive dimerization; Diastereoselective; Enantioselective; AIBN; 2,2-Azobisisobutyronitrile; BOC; tert-Butoxycarbonyl; Cbz; Benzyloxycarbonyl; COD; Cyclooctadiene; Cp; Cyclopentadienyl; DDB; 1,4-Bis(dimethylamino)-2,3-dimethoxybutane;
Recent approaches to the construction of 1-azaspiro[4.5]decanes and related 1-azaspirocycles
Keywords: Azaspirocyclic ring systems; Spirocycles; 3° Carbon center; Ac; acetyl; AIBN; azobisisobutyronitrile(2,2â²-azo(2-methylpropionitrile)); Ar; aryl; Bn; benzyl; Boc; t-butoxycarbonyl; Bu; butyl; Cbz; benzyloxycarbonyl; Cy; cyclohexyl; DBB; di-t-butylbiphen
Synthesis and biological evaluation of novel steroid-modified ether phospholipids
Keywords: Steroid ether phospolipids; Platelets; Platelet activating factor; PAF-acetylhydrolase; Periodontal disease; Ac; acetyl; Bn; benzyl; LPC; lysophosphatidylcholine; PAF; platelet-activating factor; Ph; phenyl; SM; sphingomyelin; TBAF; tetrabutylammonium flu
Naphtho[2,3-c]furan-4,9-diones and related compounds: theoretically interesting and bioactive natural and synthetic products
Keywords: Naphtho[2,3-c]furan-4,9-diones; Naphtho[2,3-c]furan-4(9H)-ones; Naphtho[2,3-c]furan; Isofuranonaphthoquinones; Ac; acetyl; AIBN; 2â²-azobis(isobutyronitrile); Ar; aryl; Bn; benzyl; BOM; benzyloxymethyl; But; tert-butyl; CSA; camphor-10-sulfonic acid; DBU
Recent advances in ether dealkylation
Keywords: O-Dealkylation; Deprotection; Debenzylation; Review; Ac; acetyl; Alloc/Aloc; allyloxycarbonyl; BMIM; 1-n-butyl-3-imidazolium; Bn; benzyl; Boc; t-butoxycarbonyl; BOM; benzyloxymethyl; Bz; benzoyl; CAN; ceric ammonium nitrate; Cbz; benzyloxycarbonyl; CSI; c
Recent developments in the Nazarov process
Keywords: Nazarov cyclisation; Divinyl ketone; Electrocyclisation; Cyclopentenone; Ar; aryl; BF3·Et2O; boron trifluoride etherate; Boc; tert-butoxycarbonyl; Bu; butyl; Cbz; benzyloxycarbonyl; Chx; cyclohexyl; Cp; cyclopentadienyl; DIB; o-diiodobenzene; Dppe; bis(d