Keywords: فرکانس گردش; HT-WGS; high-temperature water-gas shift; LT-WGS; low-temperature water-gas shift; MSR; methane steaming reforming; TPSR; temperature-programmed surface reaction; TPR; temperature-programmed reduction; TPO; temperature-programmed oxidation; TPD; temperatu
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Keywords: فرکانس گردش; Bacterial cellulose; Electrodeposition; Hydrogen evolution reaction; Platinum; Turnover frequency;
Keywords: فرکانس گردش; 4DHBP; 4,4â²-dihydroxy-2,2â²-bipyridine; 6DHBP; 6,6â²-dihydroxy-2,2â²-bipyridine; Acac; acetylacetonate; Acriphos; 4,5-bis(diphenylphosphino)acridine; Bpy; 2,2â²-bipyridine; Cp; cyclopentadienyl; Cp*; pentamethyl cyclopentadienyl; DMOA; N,N-dimethylo
Keywords: فرکانس گردش; BDC; 1,4-benzenedicarboxylate; BTC; benzenetricarboxylate; NDC; 1,4-naphthalenedicarboxylate; TPT; 2,4,6-tris(4-pyridyl)-1,3,5-triazine; MeIM; 2-methylimidazole; DOBDC; 2,5-dihydroxyterephthalate; TCPP; tetrakis(4-carboxyphenyl)porphyrin; H2bpydc; 2,2â²-
Keywords: فرکانس گردش; CuAAC; Copper-Catalyzed Azide-Alkyne Cycloadditions; PhSH; thiophenol; alloc; allylcarbamate group; DAPI; 4â²,6-diamidine-2â²-phenylindole; EtBr; ethidium bromide; TON; turnover number; GSH; glutathione; PBS; phosphate buffered saline; TPP; triphenylp
Keywords: فرکانس گردش; HER; hydrogen evolution reaction; OER; oxygen evolution reaction; ORR; oxygen reduction reaction; CO2RR; carbon dioxide reduction; EOR; alcohol oxidation reaction; CV; cyclic voltammetry; LSV; linear sweep voltammetry; CPE; constant potential electrolysis
Keywords: فرکانس گردش; 1,4-biyb; 1,4-bis(imidazol-1-ylmethyl)benzene; 2,6-ndc; 2,6-naphthalenedicarboxylate; 2-cmsnH2; 2-carboxymethylsulfanyl nicotinic acid; 3-dpye; N,Nâ²-bis(3-pyridinecarboxamide)-1,2-ethane; 4,4â²-bpy; 4,4â²-bipyridine; 4,4â²-obb; 4,4â²-oxybis(benzoate
Keywords: فرکانس گردش; TMS; thermomorphic solvent systems; TOF; turnover frequency; DMF; N,N-dimethylformamide; 1; isomeric decene mixture; 3; branched C11 aldehydes; 2; undecanal; 4; decane; BP; highboiling byproducts; v%; volume percentage; Homogeneous catalysis; Hydroformyla
Keywords: فرکانس گردش; AC; activated carbon; CNT; carbon nanotubes; EG; ethylene glycol; GEN; graphene; GIT; graphite; HPLC; high performance liquid chromatography; HY; zeolite HY; ICP-OES; inductively coupled plasma optical emission spectrometry; P80; carbon black P80; PG; pro
Keywords: فرکانس گردش; Hydrogen evolution; Tungsten carbide; Nanowall structure; Electrochemical durability; Turnover frequency;
Small-molecule models of tyrosinase: From ligand hydroxylation to catalytic monooxygenation of external substrates
Keywords: فرکانس گردش; BIMZ; bis(1-methylimidazol-2-yl)methane; BPM; 1,1â²-methylenebis-1H-pyrazole; CO; catechol oxidase; CT; charge transfer; dmBPM; 1,1â²-methylenebis(3,5-di-methyl-1H-pyrazole; DFT; density functional theory; l-DOPA; 3,4-dihydroxy-l-phenylalanine; 2,4-DTBP
Catalyst recycling-A survey of recent progress and current status
Keywords: فرکانس گردش; AAS; atomic absorption spectroscopy; AB; ammonia-borane (H3N:BH3); acac; acetylacetonate; BAIB; [bis(acetoxy)iodo]benzene; bdmi; 1-butyl-2,3-dimethylimidazolium; BARF; tetrakis-[3,5-bis(trifluoromethyl)phenyl]borate; BINAM; 1,1â²-binaphthyl-2,2â²-diam
Keywords: فرکانس گردش; Higher alcohol synthesis; Syngas; Cobalt; Copper; Cobalt carbide; Modified Fischer–Tropsch catalysts; Turnover frequency
Keywords: فرکانس گردش; Hydrogen peroxide activation; Metal complexes; Photosensitizers; Semiconductors; Redox reactions; Photocatalysis; ROS; reactive oxygen species; SOD; superoxide dismutase; Por; porphyrin; TAML; tetraamido macrocyclic ligand; DFT; density functional theory;
Keywords: فرکانس گردش; acac; acetylacetonate; All; allyl; An; methoxyphenyl; BARF; tetrakis[3,5-bis(trifluoromethyl)phenyl]borate; Bn; benzyl; Bu; n-butyl; Cp; η5-cyclopentadienyl; Cpâ²; η5-methylcyclopentadienyl; CPE; controlled potential electrolysis; CV; cyclic voltammetr
Keywords: فرکانس گردش; O2â¢â¾; superoxide; ONOO-; peroxynitrite; ClO-; hypochlorite; MnTE-2-PyP5+; Mn(III) meso-tetrakis(N-ethylpyridinium-2-yl)porphyrin (also known as AEOL10113, BMX-010); MnTE-3(or 4)-PyP5+; Mn(III) meso-tetrakis(N-ethylpyridinium-3(or 4)-yl)porphyrin;
Keywords: فرکانس گردش; Solar energy conversion; Photocurrent; Thylakoid membrane; Anthraquinone; Turnover frequency;
Keywords: فرکانس گردش; Solid acid catalysts; Catalytic activity; Turnover frequency; Reaction conditions; Biodiesel
Catalytic performance of Ru, Os, and Rh nanoparticles for ammonia synthesis: A density functional theory analysis
Keywords: فرکانس گردش; DFT; density functional theory; PED; potential energy diagram; RDS; rate determining step; TEM; transmission electron spectroscopy; TOF; turnover frequency; TS; transition state; Density functional theory; Kinetic analysis; Particle size dependence; NH3 s
Enhanced stability of Co catalysts supported on phosphorus-modified Al2O3 for dry reforming of CH4
Keywords: فرکانس گردش; BET; Brunauer-Emmett-Teller; DRM; dry reforming of methane; GC; gas chromatogram; FEG; field-emission gun; RWGS; reverse watergas shift; TEM; transmission electron microscopy; TGA; thermogravimetric analysis; TOF; turnover frequency; TPD; temperature-
Synthesis of MOFs for heterogeneous catalysis via linker design
Keywords: فرکانس گردش; MOFs; metal-organic frameworks; PCNs; porous coordination networks; PCPs; porous coordination polymers; PSM; post-synthetic modifications; SBUs; secondary building units; TCPP; tetrakis(4-carboxyphenyl)porphyrin); MMPF; metal-metalloporphyrin framework;
Quantifying the turnover frequency for ethanol electro-oxidation on polycrystalline Pt in acid and alkaline media
Keywords: فرکانس گردش; Turnover frequency; Electro-oxidation; Ethanol; Platinum; Alkaline; Acid;
Heteroleptic diimine-diphosphine Cu(I) complexes as an alternative towards noble-metal based photosensitizers: Design strategies, photophysical properties and perspective applications
Keywords: فرکانس گردش; ACN; acetonitrile; ATRA; atom transfer radical addition; bpy; 2,2â²-bipyridine; CDC; cross-dehydrogenative coupling; DCM; dichloromethane; DFT; density functional theory; DHA; dihedral angle; DMF; dimethylformamide; DSSC; dye sensitized solar cell; FC; F
Reaction mechanisms of catalytic photochemical CO2 reduction using Re(I) and Ru(II) complexes
Keywords: فرکانس گردش; 6Mesbpy; 6,6â²-mesityl-2,2â²-bipyridine; BIH; 1,3-dimethyl-2-phenyl-2,3-dihydro-1H-benzo[d]imidazole; BNAH; 1-benzyl-1,4-dihydronicotinamide; bpy; 2,2-bipyridine; CV; cyclic voltammetry; dmb; 4,4â²-dimethyl-2,2â²-bipyridine; D; electron donor; DMA; N,
Antioxidant activity of selenenamide-based mimic as a function of the aromatic thiols nucleophilicity, a DFT-SAPE model
Keywords: فرکانس گردش; GPx mimic; Nucleophilicity; Catalytic activity; Turnover frequency; Solvent assisted proton exchange; Donor-acceptor;
Exploration of high-performance W6S8-supported single-atom Rh1 catalysts for reverse water-gas shift reaction and methanol formation via DFT computational study
Keywords: فرکانس گردش; Rh1@W6S8; Reverse water-gas-shift reaction; Energetic span model; Turnover frequency; Methanol;
Green synthesis of plant supported CuAg and CuNi bimetallic nanoparticles in the reduction of nitrophenols and organic dyes for water treatment
Keywords: فرکانس گردش; Green synthesis; Bimetallic nanoparticles; Azo dyes; Turnover frequency; Re-usability of catalyst;
Effects of structure and size of Ni nanocatalysts on hydrogen selectivity via water-gas-shift reaction-A first-principles-based kinetic study
Keywords: فرکانس گردش; WGSR; water-gas shift reaction; DFT; density functional theory; BEP; Brønsted-Evans-Polanyi; TOF; turnover frequency; VASP; Vienna ab initio simulation package; GGA-PBE; generalized gradient approximation Perdew-Burke-Ernzerhof; NEB; Nudged Elastic Band;
Molecular catalysis of the electrochemical and photochemical reduction of CO2 with Fe and Co metal based complexes. Recent advances
Keywords: فرکانس گردش; TON; turnover number; TOF; turnover frequency; CS; catalytic selectivity; CV; cyclic voltammetry; SHE; standard hydrogen electrode; FE; faradaic efficiency; PS; photosensitizer; SD; sacrificial electron donor; âPS; photosensitizer excited state; PSâ;
Rearranging from 6- to 7-coordination initiates the catalytic activity: An EPR study on a Ru-bda water oxidation catalyst
Keywords: فرکانس گردش; EPR; electron paramagnetic resonance; H2bda, 2; 2â²-bipyridine-6,6â²-dicarboxylic acid; PSII; Photosystem II; WOCs; water oxidation catalysts; bpy; 2,2â²-bipyridine; bda2â, 2; 2â²-bipyridine-6,6â²-dicarboxylate; TOF; turnover frequency; TON; turnov
Carbon dioxide reduction with homogenous early transition metal complexes: Opportunities and challenges for developing CO2 catalysis
Keywords: فرکانس گردش; 18-crown-6; 1,4,7,10,13,16-hexaoxacyclooctadecane; Ac; acetyl group; bpy; 2,2â²-bipyridine; bpy-R; substituted 2,2â²-bipyridine ligand; Cp; cyclopentadienyl anion; Cpâ²; methylcyclopentadienyl anion; Cp*; pentamethylcyclopentadienyl anion; DFT; Density
Multidentate N-heterocyclic carbene complexes of the 3d metals: Synthesis, structure, reactivity and catalysis
Keywords: فرکانس گردش; δ; Chemical shift; 1D; One dimension; 2D; Two dimensions; Ac; Acetate; Acac; Acetylacetonate; Ad; Adamantyl; Ar; Aryl; BARF; Tetrakis(3,5-di-trifluoromethylphenyl)borate); Bipy; 2,2â²-bipyridine; Bu; Butyl; Bn; Benzyl; COD; Cyclooctadiene; COE; Cyclooct
Catalytic combustion of soot particulates over rare-earth substituted Ln2Sn2O7 pyrochlores (Ln = La, Nd and Sm)
Keywords: فرکانس گردش; Soot combustion; Pyrochlore; Oxygen vacancy; Turnover frequency; Catalytic activity
Facile synthesis of highly active Rh/Al2O3 steam reforming catalysts with preformed support by flame spray pyrolysis
Keywords: فرکانس گردش; Rh/Al2O3; Flame spray pyrolysis; Preformed support; Methane steam reforming; Turnover frequency
Dynamical changes of a Ni-Fe oxide water splitting catalyst investigated at different pH
Keywords: فرکانس گردش; OER; oxygen evolution reaction; ηOER; overpotential for the oxygen evolution reaction; TOF; turnover frequency; igeom.; geometric current density; imass; mass based activity; Pi; phosphate buffer; Bi; borate buffer; KOH; potassium hydroxide; DEMS; differ
Oxidative dehydrogenation of isobutane on carbon xerogel catalysts
Keywords: فرکانس گردش; Oxidative dehydrogenation; Carbon xerogels; Surface oxygen groups; Nitrogen-doping; Isobutane; Turnover frequency
Effect of synthesis temperature on the structural properties and photocatalytic activity of TiO2/SiO2 composites synthesized using rice husk ash as a SiO2 source
Keywords: فرکانس گردش; TiO2/SiO2; Rice husk ash; Terephthalic acid; Photocatalyst; Titanium tetrachloride; Turnover frequency;
Nanocatalysis: size- and shape-dependent chemisorption and catalytic reactivity
Keywords: فرکانس گردش; AFM; atomic force microscopy; BCC; body centered cubic; BE; binding energy; CN; coordination number; DRIFTS; diffuse reflectance infrared spectroscopy; DFT; density functional theory; DMF; dimethylformamide; EXAFS; extended X-ray absorption fine-structure
A novel fluidized-bed-optical-fibers photocatalytic reactor (FBOFPR) and its performance
Keywords: فرکانس گردش; Fluidized-bed-optical-fibers photocatalytic reactor; TiO2; TCE; Apparent photon quantum efficiency; Turnover frequency
Pd/C nanocatalyst with high turnover frequency for hydrogen generation from the formic acid–formate mixtures
Keywords: فرکانس گردش; Hydrogen generation; Formic acid–formate mixture; Pd/C catalyst; Turnover frequency
Theoretical investigation into the Co+ catalytic activity in the cycle reaction of N2O with C2H6 in the gas phase
Keywords: فرکانس گردش; Nitrogen monoxide; Ethane; Cycle reaction; Density functional theory; Two-state reaction; Intersystem cross; Energetic span; Turnover frequency
Kinetic and thermodynamic aspects of the electrocatalysis of acid reduction in organic solvent using molecular diiron-dithiolate compounds
Keywords: فرکانس گردش; Hydrogen production; Hydrogenase model; Molecular electrocatalyst; Overpotential; Turnover frequency;
Photocatalytic reduction of CO2 under supercritical CO2 conditions: Effect of pressure, temperature, and solvent on catalytic efficiency
Keywords: فرکانس گردش; Photocatalytic CO2 reduction; Rhenium catalyst; Supercritical CO2; Turnover number; Turnover frequency
Basic activity of Y zeolite containing alkylammonium cations in Knoevenagel condensation
Keywords: فرکانس گردش; Y zeolite; Ion exchange; Alkylammonium cations; Base catalyst; Turnover frequency
Performance of a biomimetic oxidation catalyst immobilized on silica particles
Keywords: فرکانس گردش; Biomimetic; Catalysis; Cobalt porphyrin; Immobilization; Silica particles; X-ray Photoelectron Spectroscopy; Magnetic particles; Turnover number; Turnover frequency
Nano-crystallite oriented self-assembled ZSM-5 zeolite and its LDPE cracking properties: Effects of accessibility and strength of acid sites
Keywords: فرکانس گردش; ZSM-5 zeolite; Salt-aided seed-induced synthesis; Oriented self-assembly; LDPE cracking; Acid site accessibility; Acid strength; Turnover frequency
The impact of pre-reduction thermal history on the metal surface topology and site-catalytic activity of Co/SiO2Co/SiO2 Fischer–Tropsch catalysts
Keywords: فرکانس گردش; Fischer–Tropsch; Cobalt; Calcination; Reduction; Structure sensitivity; Surface topology; Turnover frequency; CO-infrared spectroscopy
Synthesis and catalytic investigation of organophilic Pd/graphite oxide nanocomposites
Keywords: فرکانس گردش; Graphite oxide; Palladium; Nanoparticle; Alkyne hydrogenation; Turnover frequency; Selectivity
Transesterification of sunflower oil on single step sol–gel made Al2O3 supported CaO catalysts: Effect of basic strength and basicity on turnover frequency
Keywords: فرکانس گردش; Sol–gel; Calcium oxide; Alumina; Sunflower transesterification; Turnover frequency
In situ study of oxidation states and structure of 4Â nm CoPt bimetallic nanoparticles during CO oxidation using X-ray spectroscopies in comparison with reaction turnover frequency
Keywords: فرکانس گردش; In situ X-ray absorption spectroscopy; Ambient pressure X-ray photo-electron spectroscopy; Bimetallic nanoparticles; CoPt alloys; Oxidation states; Cycling pressure; CO oxidation; Turnover frequency;