کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10131545 | 1645543 | 2018 | 24 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Thermodynamic and kinetic study of CaCl2-CH3OH adducts for solid sorption refrigeration by TGA/DSC
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی انرژی
مهندسی انرژی و فناوری های برق
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Addition compounds of CaCl2 and CH3OH are promising thermochemical materials for thermal energy storage and conversion. Achievable evaporation temperatures lie within the operating range of standard building and industrial refrigeration applications. In heterogeneous gas-solid reactions the cooling power of the respective reaction pair is mainly dependent on the uptake rate of the gaseous reactant. In this paper, a comprehensive study on the influence of various procedural parameters and thermal cycling on the cooling efficiency performance of CaCl2 methanolates was carried out at material scale to provide insights on application design principles. SCPs and cooling COPs were calculated from experimental data obtained by simultaneous TGA/DSC. SCPs, averaged over a methanolation time of 60â¯min, varied between 157â¯W/kg and 366â¯W/kg, whereas maximum SCPs reached values between 232â¯W/kg and 1029â¯W/kg depending on methanol partial pressure. The results indicate possible applications with evaporator temperatures around 10â¯Â°C, as for the cooling of buildings. COPs were within the range of 0.59 and 0.76. Results showed that thermodynamic conditions and thermophysical properties of the material had a great impact on the methanolation/demethanolation reaction kinetics. Under periodic conditions a slight attenuation of the maximum cooling power was observed, whilst the more practically relevant average SCP was stable over a number of 18 cycles. With respect to application design, different regeneration (demethanolation) temperatures as well as the impact of the thermal history of the material were investigated. The reaction pair can also be used with regeneration temperatures of â¤100â¯Â°C.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Energy - Volume 230, 15 November 2018, Pages 1255-1278
Journal: Applied Energy - Volume 230, 15 November 2018, Pages 1255-1278
نویسندگان
Kathrin Korhammer, Karsten Neumann, Oliver Opel, Wolfgang K.L. Ruck,