کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10141095 | 1646055 | 2018 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Li4Ti5O12/activated-carbon hybrid anodes prepared by in situ copolymerization and post-CO2 activation for high power Li-ion capacitors
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
Hybrid anodes with Li4Ti5O12 nanoparticles uniformly embedding in a mesoporous activated carbon matrix are prepared by CO2 activation of copolymerized resorcinol and hexamethylenetetramine loaded by lithium acetate and tetrabutyl titanate. The Li4Ti5O12/activated-carbon hybrid anodes show increased capacity retention as the activated carbon content in the composite increases, although their overall specific capacity decreases gradually. The hybrid anode with an activated-carbon content of 54â¯wt% exhibits the highest capacity retention of 67% at 4â¯Aâ¯gâ1 referencing to that at 0.1â¯Aâ¯gâ1. When coupling it with commercial AC cathode, the Li-ion capacitor displays an outstanding high energy density of 38â¯Wh kgâ1 even at a high power density of 7964â¯Wâ¯kgâ1. Moreover, an energy density retention of 90.8% after 2000 cycles at 1â¯Aâ¯gâ1 is preserved, demonstrating its very stable cycle performance. The results reported in this work indicate that the Li4Ti5O12/activated-carbon hybrids prepared by the proposed copolymerization and post-activation process may be very promising anode materials of Li-ion capacitors designed for high power applications.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 401, 15 October 2018, Pages 135-141
Journal: Journal of Power Sources - Volume 401, 15 October 2018, Pages 135-141
نویسندگان
Chunhai Jiang, Jing Zhao, Huiqing Wu, Zhimin Zou, Renzhong Huang,