کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10154681 | 1666311 | 2018 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Balancing formation time and electrochemical performance of high energy lithium-ion batteries
ترجمه فارسی عنوان
تعادل زمان تشکیل و عملکرد الکتروشیمیایی از باتری های باتری لیتیوم یون بالا
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
شیمی
الکتروشیمی
چکیده انگلیسی
Most lithium-ion batteries still rely on intercalation-type graphite materials for anodes, and the formation process for them typically takes several days or even more to provide a stable solid electrolyte interphase (SEI). The slow formation step results in lower LIB production rates, requires a large number of battery cyclers, and constitutes the second highest cost during battery manufacturing. In an effort to decrease the high manufacturing cost associated with long formation times, we studied five different formation protocols in nickel-rich LiNi0.8Mn0.1Co0.1O2 (NMC811)/graphite cells where the total formation time varied from 10 to 86â¯h. Electrochemical characterization and post mortem analysis show that very long formation time do not necessarily improve long-term performance while very short formation protocols result in lithium plating and poorer electrochemical performance. We find the optimum formation cycling protocol is intermediate in length to minimize impedance growth, improve capacity retention, and avoid lithium plating.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Power Sources - Volume 402, 31 October 2018, Pages 107-115
Journal: Journal of Power Sources - Volume 402, 31 October 2018, Pages 107-115
نویسندگان
Chengyu Mao, Seong Jin An, Harry M. III, Jianlin Li, Marissa Wood, Rose E. Ruther, David L. III,