کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10235728 | 45055 | 2011 | 7 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Biolubricant synthesis using immobilised lipase: Process optimisation of trimethylolpropane oleate production
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
بیو مهندسی (مهندسی زیستی)
پیش نمایش صفحه اول مقاله

چکیده انگلیسی
Synthetic esters based on polyols and fatty acids possess suitable technical and ecological properties for applications as biolubricants, and can replace the mineral oil based lubricants in several applications. In this work, the synthesis of trimethylolpropane (TMP) esters with oleic acid using immobilised lipase B from Candida antarctica (Novozym®435) has been studied. TMP-trioleate has suitable properties for use as hydraulic fluids, especially at extreme temperatures. The effect of different reaction parameters on the reaction efficiency has been evaluated. The study showed that the formation of the triester product was facilitated at high temperature and biocatalyst concentration, as well as stoichiometric amounts of oleic acid and TMP. The product with the highest triester content exhibited the lowest pour point (â42 °C). The stability of the biocatalyst was however limited at high temperature and polyol concentration. Loss of activity during recycling of the biocatalyst at 70 °C was reduced to some extent by washing it with 2-propanol prior to subsequent run.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Process Biochemistry - Volume 46, Issue 12, December 2011, Pages 2225-2231
Journal: Process Biochemistry - Volume 46, Issue 12, December 2011, Pages 2225-2231
نویسندگان
Cecilia Orellana Ã
kerman, Anna E.V. Hagström, M. Amin Mollaahmad, Stefan Karlsson, Rajni Hatti-Kaul,