کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10239125 | 46027 | 2005 | 9 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Reductive amination of cyclopentanone
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موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
چکیده انگلیسی
The kinetics of heterogeneous catalytic reductive amination of cyclopentanone has been studied on a pilot plant PARR autoclave. N-cyclopentyliminocyclopentane was detected as the main intermediate in a reaction mixture. It was found that, at the given conditions, the main intermediate does not form the undesirable N,N-dicyclopentylamine but undergoes slow hydrolysis, and the desired product, cyclopentylamine, results in a good yield. Slight amounts of by-products such as cyclopentanole and N,N-dicyclopentylamine were obtained. The experimental data were confronted with the suggested kinetic model.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Applied Catalysis A: General - Volume 286, Issue 2, 7 June 2005, Pages 202-210
Journal: Applied Catalysis A: General - Volume 286, Issue 2, 7 June 2005, Pages 202-210
نویسندگان
P. Doležal, O. Machalický, M. Pavelek, P. Kubec, K. Hrádková, R. Hrdina, R. Å uláková,