کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10244852 | 47706 | 2005 | 11 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Carbon-supported Pt-Sn electrocatalysts for the anodic oxidation of H2, CO, and H2/CO mixtures. Part I. Microstructural characterization
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Carbon-supported Pt-Sn electrocatalysts for the anodic oxidation of H2, CO, and H2/CO mixtures. Part I. Microstructural characterization Carbon-supported Pt-Sn electrocatalysts for the anodic oxidation of H2, CO, and H2/CO mixtures. Part I. Microstructural characterization](/preview/png/10244852.png)
چکیده انگلیسی
High-resolution transmission electron microscopy (HRTEM), microchemical analysis by X-ray emission spectroscopy (EDS), and X-ray diffraction (XRD) were used to characterize the composition, size, distribution, and morphology of the phases present in three different carbon-supported Pt-Sn catalysts. The catalysts had nominal Pt/Sn atomic ratios of 1:1 (500N and 900N samples) and 3:1 (E270 sample). The 1:1 catalyst sample heat-treated at 500â°C (500N) contained a Pt-rich fcc alloy phase (a0=0.3965nm) and tetragonal SnO2. The sample from the same precursors heat treated at 900â°C (900N) consisted of stoichiometric hexagonal PtSn, a nearly stoichiometric Pt3Sn fcc phase (a0=0.3988nm), and tetragonal SnO2. Neither pure tin nor pure platinum particles were detected in any of the catalysts. The 3:1 catalyst sample reduced in H2 at 270â°C (E270) was composed entirely of the stoichiometric Pt3Sn cubic phase (a0=0.3998nm). The Pt3Sn-type particles are predominantly single nanocrystals with mean diameters of â¼4nm (for the catalysts E270 and 500N) and â¼5nm (for the catalyst 900N), whereas the PtSn particles were larger. The Pt3Sn-type particles in 500N and 900N were generally highly faceted, with {111} and {200} facets, whereas the E270 catalyst had generally a smooth spheroidal outline. Whereas the Pt3Sn particles in the E270 and 900N catalysts were equiaxed, in the 500N catalyst the alloy particles had uniquely elongated (e.g., ellipsoidal) shapes.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 232, Issue 1, 15 May 2005, Pages 199-209
Journal: Journal of Catalysis - Volume 232, Issue 1, 15 May 2005, Pages 199-209
نویسندگان
V. Radmilovic, T.J. Richardson, S.J. Chen, P.N. Jr.,