کد مقاله | کد نشریه | سال انتشار | مقاله انگلیسی | نسخه تمام متن |
---|---|---|---|---|
10245107 | 47713 | 2005 | 15 صفحه PDF | دانلود رایگان |
عنوان انگلیسی مقاله ISI
Synthesis of carbon nanofibers: effects of Ni crystal size during methane decomposition
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کلمات کلیدی
موضوعات مرتبط
مهندسی و علوم پایه
مهندسی شیمی
کاتالیزور
پیش نمایش صفحه اول مقاله
![عکس صفحه اول مقاله: Synthesis of carbon nanofibers: effects of Ni crystal size during methane decomposition Synthesis of carbon nanofibers: effects of Ni crystal size during methane decomposition](/preview/png/10245107.png)
چکیده انگلیسی
The effect of the crystal size of Ni on the growth of carbon nanofibers (CNFs) was studied in a tapered oscillating element microbalance reactor. Small Ni crystals yield a low growth rate and fast deactivation and thus a low final yield of CNF. Large Ni crystals reduce the growth rate because of low surface area. An optimum growth rate and yield of carbon nanofibers can be achieved on optimally sized Ni crystals (around 34 nm). A model has been proposed for interpreting the kinetic effects of the Ni crystal size based on a detailed mechanism of the carbon nanofiber growth. The reduced coking rate on a small-sized Ni crystal is a result of increased saturation concentration of CNF and thus a low driving force for carbon diffusion through the Ni crystals. As a consequence, the surface coverage of carbon increases, which enhances the formation of encapsulating carbon and thus the deactivation. Both the low initial coking rate and the fast deactivation result in a low yield of carbon nanofibers on small-sized crystals. The results also indicate that hydrogen has a significant effect on the formation of CNF, and an optimum partial pressure of hydrogen exists for the CNF growth.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Journal of Catalysis - Volume 229, Issue 1, 1 January 2005, Pages 82-96
Journal: Journal of Catalysis - Volume 229, Issue 1, 1 January 2005, Pages 82-96
نویسندگان
De Chen, Kjersti O. Christensen, Ester Ochoa-Fernández, Zhixin Yu, BÃ¥rd Tøtdal, Nieves Latorre, Antonio Monzón, Anders Holmen,