کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10272625 461190 2011 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Chemical - Looping with oxygen uncoupling using Mn/Mg-based oxygen carriers - Oxygen release and reactivity with methane
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Chemical - Looping with oxygen uncoupling using Mn/Mg-based oxygen carriers - Oxygen release and reactivity with methane
چکیده انگلیسی
Chemical-looping combustion with oxygen uncoupling (CLOU) is a method for combustion of solid and gaseous fossil fuels, which enables easy separation of carbon dioxide from the gaseous product mixture. In contrast to the related chemical-looping combustion (CLC) technology where gaseous or gasified fuels react directly with oxygen carriers, CLOU processes require oxygen carrier materials to be able to release oxygen in the fuel reactor and to regenerate by re-oxidation in oxygen-rich atmosphere in the air reactor at elevated temperature. Oxygen uncoupling properties and reactivities for methane combustion of 12 oxygen carrier particles, produced from mixtures of manganese and magnesium oxides with optional addition of titanium dioxide or calcium hydroxide, are investigated in a quartz batch reactor at 810 °C, 850 °C, 900 °C and 950 °C. All investigated oxygen carriers have oxygen release characteristics. The addition of calcium hydroxide facilitates oxygen release and combustion of methane, whereas addition of titanium dioxide does not have a pronounced effect on either oxygen uncoupling or reactivity of the oxygen carrier. In general, particles with greater extent of oxygen release have superior methane combustion properties.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 90, Issue 3, March 2011, Pages 941-950
نویسندگان
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