کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10272679 461190 2011 11 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Application of the Shvo catalyst in homogeneous hydrogenation of bio-oil obtained from pyrolysis of white poplar: New mild upgrading conditions
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Application of the Shvo catalyst in homogeneous hydrogenation of bio-oil obtained from pyrolysis of white poplar: New mild upgrading conditions
چکیده انگلیسی
Upgrading of bio-oils obtained from the fast pyrolysis of biomasses requires the development of efficient catalysts able to work under mild conditions and to cope with the complex chemical nature of the reactant. The present work focuses on the use of the ruthenium based Shvo homogeneous catalyst for the hydrogenation of model mixtures (vanillin, cinnamaldehyde, methylacetophenone, glycolaldehyde, acetol, acetic acid) and of a real bio-oil. The hydrogenation of model compounds has been investigated both in mono- and biphasic mixtures under a P(H2) = 10 atm in the temperature range of 90-145 °C varying the substrate to catalyst molar ratio from 2000:1 to 200:1. Employing the most active reaction conditions (substrate/catalyst 200:1, T = 145 °C, P(H2) = 10 atm) the Shvo catalyst maintains its performances under acidic “bio-oil conditions” leading to the almost quantitative conversion of the polar double bonds within 1 h. The activity of the Shvo catalyst was also investigated for the hydrogenation of a bio-oil from poplar in solvent free conditions. Hydrogenation deeply changed the chemical nature of the pyrolysis oil. Aldehydes, ketones and non-aromatic double bonds were almost totally hydrogenated. The catalytic system also promoted the hydrolysis of sugar oligomers into monomers.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 90, Issue 3, March 2011, Pages 1197-1207
نویسندگان
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