کد مقاله کد نشریه سال انتشار مقاله انگلیسی نسخه تمام متن
10272951 461194 2011 10 صفحه PDF دانلود رایگان
عنوان انگلیسی مقاله ISI
Measures to reduce chlorine in deposits: Application in a large-scale circulating fluidised bed boiler firing biomass
موضوعات مرتبط
مهندسی و علوم پایه مهندسی شیمی مهندسی شیمی (عمومی)
پیش نمایش صفحه اول مقاله
Measures to reduce chlorine in deposits: Application in a large-scale circulating fluidised bed boiler firing biomass
چکیده انگلیسی
Combustion of biomass with a high content of alkali (mainly potassium, K) and chlorine (Cl) can result in operational problems including deposit formation and superheater corrosion. Among the measures applied to decrease such problems are co-combustion and the use of additives. The positive effects of these measures are to a large extent either sulphation of the alkali chlorides (KCl) to less corrosive alkali sulphates or capture of alkali from KCl during release of HCl. A test campaign was carried out in a large-scale circulating fluidised boiler fired with biomass where the measures applied were sulphation by ammonium sulphate and co-combustion with peat. Their performance was evaluated by means of several advanced measurement tools including: IACM (on-line measurements of gaseous KCl); a low-pressure impactor (size distribution and chemical composition of extracted fly ash particles) and deposit measurements (chemical composition in collected deposits). The overall performance was better for ammonium sulphate, which significantly lowered KCl in the flue gas. Meanwhile no chlorine was found in the deposits. Only a minor reduction of gaseous KCl was obtained during co-combustion with peat although the chlorine content in the deposits was greatly reduced. These findings were supported by the results from the impactor measurements.
ناشر
Database: Elsevier - ScienceDirect (ساینس دایرکت)
Journal: Fuel - Volume 90, Issue 4, April 2011, Pages 1325-1334
نویسندگان
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