Advanced design of Chinese traditional materials for the conservation of historic stone buildings

The conservation of historic stone buildings and sculptures is recently receiving growing attention and becoming a focus of research because of rapid changes in weather conditions (pollution, acid rain, etc.). Presently, techniques for stone conservation primarily involve the use of organic coating treatments, but their side effects have been recognized. In contrast, some traditional materials used in historic stone buildings function well for thousands of years. In this paper, we report our research on the reasons why traditional protective materials can provide an unexpected long-term protection. First, calcium carbonate was prepared according to a formula for making Chinese traditional consolidating materials, and its structure and morphology were examined by different instruments. Second, the reinforcing effectiveness of the prepared CaCO3 powders was tested and analyzed by investigating its surface characteristics. The experimental results reveal that a biocontrolled process occurs, in which an organic template can induce the precipitation of a mineral structure, which in turn results in a great improvement in the conservation of the historic stone buildings protected by these traditional protective materials. This provides a contribution toward the development of new researches on biocontrolled processes and on some protective materials with excellent performance through biocontrolled synthesis.

► We demonstrate the advantages of Chinese traditional materials for stone conservation.
► The organic components act as template.
► The structure of inorganic minerals is induced to change.
► A biocontrolled process occurs in the process of stone conservation.
► This provides an unexpected long-term protection.